Introduction to Bioorganic Chemistry and Chemical Biology: Chapter 4 Answers
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Course
CHEM180 (CHEM180)
Institution
British Columbia Institute Of Technology (BCIT
)
Book
Introduction to Bioorganic Chemistry and Chemical Biology
Answer 4.1
The bulky tert-butyl group has a strong equatorial preference, the following two conformations will be predominant. The anti isomer cannot hydrolyze through neighboring group participation; the syn isomer can hydrolyze through neighboring group participation.
OCH3
-O P O O
:O- anti
...
introduction to bioorganic chemistry and chemical biology answers to chapter 4
answer 41 the bulky tert butyl group has a strong equatorial preference
the following two conformations will be predom
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Introduction to Bioorganic Chemistry and Chemical Biology 1
Answers to Chapter 4
(in-text & asterisked problems)
Answer 4.1
The bulky tert-butyl group has a strong equatorial preference, the following two
conformations will be predominant. The anti isomer cannot hydrolyze through
neighboring group participation; the syn isomer can hydrolyze through neighboring
group participation.
er as
co
5' N N N N N N N N N N
four types of unpaired bases: A, C, G, or T
eH w
3' N N N N N N N N N
N
o.
rs e twelve types of mis-matches:
A•A, A•C, A•G, C•A, C•C, C•T, G•A, G•G, G•T, T•C, T•G, T•T
ou urc
Total possibilities = 47• 44• 12
= 411• 12
o
= 50,331,648
Introduction to Bioorganic Chemistry and Chemical Biology | A4100
aC s
Van Vranken & Weiss | 978-0-8153-4214-4
Answer 4.6
vi y re
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