Samenvatting Organische chemie: alle te kennen reacties
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Course
Bio-organische Chemie (G000714A)
Institution
Universiteit Gent (UGent)
Book
Inleiding in de bio-organische chemie
In dit document staan alle reacties die gekend moeten zijn voor het examen Organische Chemie voor diergeneeskunde 1e bachelor. Door deze samenvatting heb ik het examen in één keer gehaald!
in Pd : de
1) ⇐ c
/
→ 1C
\ -0
-
( +0 katalysator ,
deze is nodig om
✓ '
' , activeringsenergie te
overbruggen
C-
g-
-
g- Ç
-
- -
,
'
i. ì
÷
- .
c-
/ Pd
-
1-12
-
\ -0 | |
2) / C- ( +0 → H
-
H -
C -
C -
/ I I I
-
C- C-
( C
-
- _ -
-
1 '
, t
ij
ijijIJ
ijij ij
, Additie van zuren aan alkenen =
elektrofiele additie
-0
1) Het → Ht + U
1
t
III
'
di
' '
2) →
g- c- c
- -
-
I I ④ 1
↳
Pluslading OP meest
gesubstitueerde C- atoom
1
ÉF |
' ' 1
3) -
c- c -
→ -
c- c- c- H
1 +0 1 '
{p
'
Reactie met 42504 (geconcentreerd)
-0 ④
1) Hzsoy →
Hsoy t H
'
& Ê IF
2) c. If c-
- -
→ -
-
I '
I
°
Ì o
° "
t °"
④
Ê &
" ' ,
3) -
c- -
? + s
_
→ -
c- c- c- +
É
' "
j it
' '
0
is .
H
' ' '
t 0
°"
" -
C -
C -
C -
c- Ê
' ' _
s
i
,
4) - -
c- +
"
→ ,
g
H
CÉ
' ' 0
'
H
0=5--0
ÒH
Reactie met 42504 (verdund)
↳ hierb zal water
reageren i. P .
v Hz 504
I I I
H2O
⑦
É
1 C -
C C -
3)
- -
-
C -
C -
-
→
I I I
µ H
I I
10+0
/ |
H H
I
At
I I I I I
C C C → C C C +
4)
- - - - -
- -
-
I I I ' t
t,
107
" 0
'
/ 1
H
H H
Dimerisatie van alkenen = 2 alkenen koppelen
↳ kan alleen plaatsvinden als :
•
alkeen + zure
katalysator (meestal Hzsoy) aanwezig is
• in solvent zonder nucleofiele eigenschappen
'
-
c- -
ì .
IM I I I
g) -
C ÷ C
-
D -
C
-
-
C. ⑦
1 -0 |
ç g-
- - -
ij
ij
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