Summary

Samenvatting Organische chemie

0 purchase

Module
Organische Chemie (V3A547)

Institution
Katholieke Hogeschool VIVES (VIVES)

De nomenclatuur van de organische moleculen wordt behandeld. Daarnaast komen de fysische eigenschappen beperkt aan bod. Een belangrijk pakket vormt de chemische reacties die plaatsvinden in de organische chemie. De link wordt gelegd naar de cursus biochemie. Volgende hoofdstukken worden besproke...

[Show more]

Preview 4 out of 133 pages

View example

Uploaded on January 22, 2022
Number of pages 133
Written in 2021/2022
Type Summary

chemie
organische chemie
reacties
structuur
biotechnologie roeselare
vives

Institution
Katholieke Hogeschool VIVES (VIVES)
Education
Agro-en Biotechnologie
Module
Organische Chemie (V3A547)

$13.46

Also available in package deal from $18.14

Add to cart

Save

100% satisfaction guarantee
Immediately available after payment
Both online and in PDF
No strings attached

Also available in package deal (3)

Organische chemie + stappenplan nomenclatuur - reacties

$ 19.89 $ 18.14 2 items

1. Summary - Organische chemie
2. Other - Organische chemie reacties
Show more

Chemiebundel

$ 43.88 $ 29.27 4 items

1. Summary - Analytische chemie
2. Summary - Organische chemie
3. Other - Organische chemie reacties
4. Summary - Anorganische chemie
Show more

Bundel Organische chemie

$ 30.41 $ 33.96 4 items

1. Other - Verbetersleutel organische chemie
2. Summary - Organische chemie
3. Other - Organische chemie reacties
4. Other - Oefeningen nomenclatuur - reacties
Show more

SAMENVATTING ORGANISCHE CHEMIE
INHOUD

Chemische reactiviteit en stabiliteit ........................................................................................................................ 8
Arrhenius ............................................................................................................................................................. 8
Brondsted en Lowry ............................................................................................................................................ 9
Lewis.................................................................................................................................................................... 9
Elektrofiel – Neutrofiel ...................................................................................................................................... 10
Reactieve koolstofintermediaren ..................................................................................................................... 11
Mesomerie (uitleggen op examen) ................................................................................................................... 12
Kenmerken van mesomere structuren (niet van buiten leren, wel toepassen) ........................................... 13
Voorwaarden mesomerie ............................................................................................................................. 13
Alkanen ................................................................................................................................................................. 14
Nomenclatuur ................................................................................................................................................... 14
Te volgen systeem ......................................................................................................................................... 14
Isomeren ........................................................................................................................................................... 17
Isomeren heptaan (9) .................................................................................................................................... 17
Bouw van alkanen ............................................................................................................................................. 17
CH4 – methaan .............................................................................................................................................. 17
Conformaties van alkanen ................................................................................................................................ 18
Energiediagram rotatie rond C – C in ethaan (examen bespreek) ................................................................ 19
Butaan ........................................................................................................................................................... 19
Fysische eigenschappen .................................................................................................................................... 20
Reacties met alkanen ........................................................................................................................................ 20
Chlorering van methaan (examen).................................................................................................................... 20
Reactie gebeurt in 3 stappen ........................................................................................................................ 20
Stap 1: Initatie: Cl2 breken............................................................................................................................. 21
Stap 2: Propagatie ......................................................................................................................................... 21
Stap 3: Terminatie ......................................................................................................................................... 22
Chlorering van methaan (samengevat) ......................................................................................................... 22
Chlorering van hogere alkanen ......................................................................................................................... 22
Ethaan ........................................................................................................................................................... 22
Classificatie .................................................................................................................................................... 23
Biologische eigenschappen alkanen.................................................................................................................. 24
Cycloalkanen ......................................................................................................................................................... 25
Heterocyclische moleculen (Van buiten leren) ............................................................................................. 26

1

, Cycloalkylgroepen – cyclopropyl ....................................................................................................................... 26
Geometrische isomerie ..................................................................................................................................... 27
Vorm en eigenschappen cyclopropaan ............................................................................................................. 27
Vorm en eigenschappen cylobutaan ................................................................................................................. 28
Vorm en eigenschappen cyclopentaan ............................................................................................................. 28
Cyclohexaan ...................................................................................................................................................... 29
Menthol en isomenthol gunstigst, Waarom? ............................................................................................... 30
Polycyclische verbindingen ............................................................................................................................... 31
Alkenen en Alkynen .............................................................................................................................................. 32
Alkenen ......................................................................................................................................................... 32
Bouw van alkenen – geometrische isomerie .................................................................................................... 33
Chemie van het zien ...................................................................................................................................... 33
Nomenclatuur ................................................................................................................................................... 34
Nomenclatuur – oefeningen ......................................................................................................................... 34
E, Z – nomenclatuur ...................................................................................................................................... 35
Isomeren C4H8 ............................................................................................................................................... 35
Stabiliteit ........................................................................................................................................................... 36
Reacties van alkenen ......................................................................................................................................... 38
Hydrogenering van alkenen – additie van H2 ............................................................................................... 38
Voorbeeld hydrogenering – elektrofiele additie van Zuur HCl ..................................................................... 39
Additie van zuren .............................................................................................................................................. 40
Verklaring regel van Markovnikov ................................................................................................................ 41
Voorbeeld van additie van zuren .................................................................................................................. 41
additie van zuren energiediagram (Kunnen uitleggen examen) ................................................................... 42
Dimerisatie van alkenen .................................................................................................................................... 43
Oefening: reactie van 1 penteen in zuurmilieu ............................................................................................. 44
Omleggingsreacties van carbokation ................................................................................................................ 45
Additie van halogenen ...................................................................................................................................... 46
Oxidatie van alkenen ......................................................................................................................................... 48
Epoxidatie...................................................................................................................................................... 48
Vorming van vicinale alcoholen .................................................................................................................... 49
Ozonolyse ...................................................................................................................................................... 49
Syn – en anti – additie ....................................................................................................................................... 50
Reacties van C – atoom van dubbele binding ............................................................................................... 51
Alkynen ................................................................................................................................................................. 53
Hydrogenering van alkenen .............................................................................................................................. 53
Elektrofiele additie van alkynen ........................................................................................................................ 54

2

, Zuurtegraad van alkynen .................................................................................................................................. 55
Dienen en polymeren ............................................................................................................................................ 55
Dienen ............................................................................................................................................................... 55
Additiereacties van butadieen .......................................................................................................................... 56
Elektrofiele additie ........................................................................................................................................ 56
Diels alder reactie ......................................................................................................................................... 56
Reactie van butadieen en maleinezuuranhydride ........................................................................................ 57
Organochloor – insecticiden ......................................................................................................................... 57
Polymeren ......................................................................................................................................................... 58
Polymeren ..................................................................................................................................................... 59
Structuur en eigenschappen polymeren ....................................................................................................... 60
Oriëntatie ketens .......................................................................................................................................... 60
Fysische eigenschappen → 3 types van polymeren ...................................................................................... 60
Terpenen en steroïden .......................................................................................................................................... 61
Belang mono sesqui en diterpenen .............................................................................................................. 62
Carotenoïden ................................................................................................................................................ 62
Steroïden ....................................................................................................................................................... 62
Emulsie van vetten ........................................................................................................................................ 63
Planten en insectensterioden (1 voorbeeld kennen examen) ...................................................................... 63
Geurstoffen en communicatie ...................................................................................................................... 63
Aromaten .............................................................................................................................................................. 64
Benzeen en aromaticiteit .................................................................................................................................. 64
Benzeen ......................................................................................................................................................... 64
Nomenclatuur ................................................................................................................................................... 65
Nomenclatuur – plaats .................................................................................................................................. 65
Benzeen als substituent ................................................................................................................................ 65
Nomenclatuur ............................................................................................................................................... 66
Fenolen en anilinen ............................................................................................................................................... 66
Nomenclatuur ................................................................................................................................................... 66
Nomenclatuur – oefeningen ......................................................................................................................... 67
Stereochemie ........................................................................................................................................................ 67
Symmetrie en enantiomeren ............................................................................................................................ 68
Configuratie en enantiomeren .......................................................................................................................... 69
R – S nomenclatuur ....................................................................................................................................... 69
Eigenschappen enantiomeren .......................................................................................................................... 70
Diastereomeren en mesoverbindingen ............................................................................................................ 70
Diastereomeren eigenschappen ................................................................................................................... 70

3

, Halogeenalkanen .................................................................................................................................................. 71
Voorkomen........................................................................................................................................................ 71
Nomenclatuur ................................................................................................................................................... 72
Triviale namen ............................................................................................................................................... 72
Nomenclatuur – oefeningen halogeenalkanen ............................................................................................. 73
Fysische eigenschappen – Halogeenalkanen .................................................................................................... 73
Reacties met halogeenalkanen ......................................................................................................................... 74
Nucleofiele substitutie .................................................................................................................................. 74
Vormen Nucleofiele substitutiereacties ............................................................................................................ 75
Wanneer welke reactie? ............................................................................................................................... 75
Sn1 – mechanisme – 2 stappen......................................................................................................................... 76
Stap 1 ............................................................................................................................................................ 76
Stap 2 ............................................................................................................................................................ 76
Snelheid Sn1 – mechanisme.......................................................................................................................... 76
Energiediagram Sn1 – mechanisme .............................................................................................................. 77
Sn2 – mechanisme – 1 stap ............................................................................................................................... 78
Voorbeeld Sn2 – mechanisme....................................................................................................................... 78
Snelheid Sn2 – mechanisme.............................................................................................................................. 78
Energiediagram Sn2 – mechanisme .............................................................................................................. 79
Stereochemie van nucleofiele substitutie ......................................................................................................... 79
Factoren die reactiemechanisme (Sn1) van nucleofiele substitutie bepalen ................................................... 80
Structuur halogeenalkaan ............................................................................................................................. 80
Aard oplosmiddel .......................................................................................................................................... 81
Factoren die reactiemechanisme (Sn2) van nucleofiele substitutie bepalen ................................................... 82
Nucleofielsterkte en basesterkte ...................................................................................................................... 82
Aanwezigheid van grote groepen ................................................................................................................. 83
Oplosmiddel .................................................................................................................................................. 84
Nucleofiele substitutie in biologische systemen ............................................................................................... 84
Mosterdgas ................................................................................................................................................... 85
Eliminatiereactie ............................................................................................................................................... 85
E1 – mechanisme .......................................................................................................................................... 86
E2 – mechanisme .............................................................................................................................................. 87
E2 – eliminatie – stereospecifiek................................................................................................................... 87
Alcoholen en thiolen ............................................................................................................................................. 88
Alcoholen .......................................................................................................................................................... 88
Thiolen .............................................................................................................................................................. 88
Nomenclatuur – alcoholen ................................................................................................................................ 88

4

The benefits of buying summaries with Stuvia:

Guaranteed quality through customer reviews

Stuvia customers have reviewed more than 700,000 summaries. This how you know that you are buying the best documents.

Quick and easy check-out

You can quickly pay through credit card for the summaries. There is no membership needed.

Focus on what matters

Your fellow students write the study notes themselves, which is why the documents are always reliable and up-to-date. This ensures you quickly get to the core!

Frequently asked questions

What do I get when I buy this document?

You get a PDF, available immediately after your purchase. The purchased document is accessible anytime, anywhere and indefinitely through your profile.

Satisfaction guarantee: how does it work?

Our satisfaction guarantee ensures that you always find a study document that suits you well. You fill out a form, and our customer service team takes care of the rest.