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Complete Lecture series - Notes Organic Chemistry Practical $17.26   Add to cart

Class notes

Complete Lecture series - Notes Organic Chemistry Practical

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These documents are completely covering the lectures, along with explanation from the book which are necessary to know for the exam Organic Chemistry Practical.

Last document update: 1 year ago

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  • January 30, 2023
  • January 30, 2023
  • 29
  • 2021/2022
  • Class notes
  • Prof dr a j minnaard
  • All classes
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Photopharmacology usingtighttocontrolthe activityofdrugsbythe incorporationofmolecular
switchesintotheirstructures
photo



N N

µ µ
KKt
É Et temperature and the substituants of



Eg
en que p

spahybridized flatmolecule withoutrotation
at N Nrdoublebond

When weshinelightwitha certainwavelengthyou'll
givesomuchenergythat it wilflip Aftertheflip it won't
beflippedagainsincecis trans flipsbothhavedifferentwavelengths There is an energydifferencebetween

thetranscompound ciscompound that
youalready alsoknowthat cis is higherinenergyandslowly
will fallbacktotrans



Seekingstericdashintrans




Äii iii
iii

iii i
Moleculesshould
fit into a pocketofanothermoleculeofinterest Itshouldhavetherightshapeofcis trans




Withthismethodyouhavethepossibilityofactivatingdrugsinbodypartsofinterest You'llhavetotakethemedicine
and then activateit byshininglight to the particularbodyspot Deactivating also is possible

, Organic Chemistry Practical
Series 1 Introduction conjugation aromaticity

paracetamol impurities synthesis ofdiclofenac



1 Introduction

Drawing bonds

CC SCC

every singlebondhereis C C 0 bond

every double bond
here is EC a bond ÊÊ

Drawing reactions


Nu Ä Important isthat
youdraw onestepat a time
Thereactionisalwaysfromthe
electronsofthenucleophile




this carbonylis electrophilic bethe oxygenpulls e towardsitselfaway
his iselectrophilic

fromthecarbonThismakes a dipolemoment partiallynegative up and partially

positive down

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