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IB chemistry HL notes (grade 7 achieved)

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IB chemistry HL notes with important things to memorise.

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  • May 7, 2023
  • 27
  • 2021/2022
  • Class notes
  • Dr. shaji
  • All classes
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,1. Stoichiometric relationships
Element The mole concept
.
a single pure substance made of only one type of atom No . of particles = no . Of moles × Avogadro constant
,

( n ) ( L )

G. 02 × 1023
Compound Mass of 1 molecule =
g.o×o }

chemical combination of different elements
,
containing fixed

ratio of atoms

Relative atomic mass
'
pure substance formed when two or more elements combine chemically
.
average mass of the naturally occurring isotopes of the element

relative to the mass of ¥ of an atom of carbon -
12



Mixtures
-

composed of two or more substances in which no chemical
Relative formula mass
combination has occurred .
sum of weighted average of masses of atoms in a formula

unit relative to % Of an atom of carbon -12

1
Homogeneous mixture
-

has uniform composition and properties throughout
-
can be separated by physical means
Mole
.
the amount of substance that contains 6.02 ✗ 1023 particles
2 Heterogeneous mixture
.
has non - uniform composition and properties is not the same


throughout Molar mass
,
mass of one mole of any substance
.
can be separated by mechanical means


mass (g)
NO Of moles =
ass
.
'
( 9m01 )
_


States of matter

solid liquid gas

arrangement close packed more spaced spread out


inter particle weak negligible Empirical formula
force strong
-
simplest whole number ratio of atoms


movement vibrate at fixed slide over move freely
position
Molecular formula

actual / real no Of atoms
shape / Volume fixed fixed shape fixed
'

no no
.




fixed V01 Shape / V01


Calculation Of Empirical formula

kinetic theory of matter
element
.
average kinetic theory of particle is directly related to the molar mass
010 by mass n =
temperature empirical formula mass
Ar
-
temperature is a measure of average kinetic energy of
moles
particles of a substance
/ by smallest no




Diffusion
.
particles of a substance become evenly distributed as a
Limiting reactant
,
-
determines the amount of product that can form
result of their random movements




Theoretical yield
-

quantity of product that can form from complete conversion

changes of state of limiting reactant




so ,
,Éiiga ,
0/0 yield =
e×Perimen+atY
theoretical yield
× you %




ᵗ"É
law
Avogadro 's
-

equal volumes of all gases when measured at same temp
,

and pressure ,
contain equal number of particles
endothermic
exothermic
.
V x n


Volume
no - Of moles of gas =

molar volume


Heating curve molar volume is the volume occupied by one mole of
any
.




gas


B / C
$
C -1g
,
Mp / FP

, conditions STP
of Ideal gas
22.7 dm"mor-I obeys the ideal DV=nRT under all conditions
gas law
273K /00C ·no such thing as an ideal gas
100kPa known as
all gases are real gases


A



200
Gas laWS high temp
1000K
Gas behave like an ideal gas at
Boyle's Law
- deal gas
low pressure
relationship between volume and pressure
p/pa
·



pct
PV a
=
constant


2 Assumptions made in describing ideal gas in kinetic molecular theory
volume of gas particles is negligible (molecules have no volume
p P PV
2
there are no attractive forces between particles

I
↓ P



Charle's Law
p
zV
+
-
b RT
=




relationship between volume and temperature
VxT Concentration a
of solution

I a
= constant is
solvent p resentin
component the quantity
greatest




V V
n cV
=


gdm moldm
=
mass required const x
Mr Xthe
on

T(0 T(K)

Dilution of solutions

C,V, (zVz
=




Gay-Lussac's law

·relationshipbetween pressure and temperature

pxT
I a
=
constant
Volumetric Analysis
T
determine the concentration a
of solution




P P
Titration
T(0) T(k) ·used determine
to the reacting volumes precisely

changes colour at its end point




Relationship between P.V and + To find concentration
unknown acid
of

P conch
n(alkali) = vo l
x

ifpressure
PCI a
of gas is doubled c onstant
at
n(acid) =

temperature then volume will be halved
[acid] I



V Acid Alkali->
+
Salt +H20


V
VaT


if temperature is doubled the volume will double
Back titration
used when the concentration is too small
T(K


P
pdT mass s olute
of
concentration in ppm = 106
is doubled will double mass s olution
of
if temperature the pressure

T/K


=volumeofgasan
combined gas laws


E a
=
constant


xHy (x
1)02xCO2 Hc0
#Y P2V
+ + +




=




19 1000mg
=




The ideal gas equation
19 0.001
=


kg
PV n RT
=




pressure Pa
= kPa:X
by 103
volume =
m3 am3: -103 cm3: =106
m oleS n
no. of =




temperature K
= 0: +
273


PV =
RT Mr =
m.piT RT =
d =
density

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