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CARBANIONS
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CARBANION CHEMISTRY STABILITY OF CARBANIONS REXNS .
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____________________________________________________________________________________________________Subject Chemistry
Paper No and Title Paper 5: Organic Chemistry-II (Reaction Mechanism-1)
Module No and Title Module 7: Generation, structure, stability and reactivity of
carbanions
Module Tag CHE_P5_M7
CHEMISTRY PAPER No.5:Organic Chemistry-II (Reaction Mechanism-1)
MODULE No.7: Generation, structure, stability and
reactivity of carbanions
, ____________________________________________________________________________________________________
TABLE OF CONTENTS
1. Learning Outcomes
2.Introduction
3. Generation of a carbanion
3.1 Proton abstraction
3.2 Decarboxylation
3.3 Addition of nucleophile to alkene
3.4 Formation of organometallic compounds
3.6 Ylides
3.7 Dithiane
3.8 Carbanions of weak CH acids
3.9 Chiral carbanion
4. Features of carbanion
5. Stability of carbanion
5.1 Inductive effect
5.2 Extent of conjugation of the anion
5.3 Hybridization of the charge-bearing atom
5.4 Aromaticity
6. Reactivity of carbanion
6.1 Displacement reaction
6.2 Elimination reaction
6.3 Condensation reaction
6.4 Addition reaction
6.5 Rearrangement reaction
6.6Anionic polymerisation reaction
6.7 Wittig reaction
7. Summary
CHEMISTRY PAPER No.5:Organic Chemistry-II (Reaction Mechanism-1)
MODULE No.7: Generation, structure, stability and
reactivity of carbanions
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