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CHEMISTRY OF BORANES

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The chemistry of boranes involves the study of chemical compounds containing boron and hydrogen atoms. Boranes exhibit unique structures and reactivity, making them a fascinating subject within the broader field of inorganic chemistry. Here's an overview of the chemistry of boranes: 1. Basic Str...

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  • January 5, 2024
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  • 2022/2023
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Programme Code- MSCCH-17/18/19
Course Code-CHE-501

Unit- 19 Metal Cluster




Presented by-
Dr. Charu C. Pant
Department of Chemistry
Uttarakhand Open University, Haldwani

,Introduction
Boranes
Nomenclature
Classification
Wade’s Rules
Styx Numbers
Diborane
Structure and Bonding
Reactions
Carboranes
Synthesis and Reactions
Carborane Ligands
Metalloboranes
Metallacarboranes
Compounds with metal-metal multiple bonds
Polyoxometalates (Isopoly and Heteropoly acids)
Summary
Terminal Questions
Answers

, OBJECTIVES:
The chapter covers boranes, carboranes, metalloboranes,
metallocarboranes along with various aspects of isopoly
and heteropoly acids. This chapter aims at providing a
good understanding of metal cluster compounds with
respect to their synthesis, structure and properties.
Typesboranes, carboranes their synthesis and various
bonding aspects in these class of compounds will be
focused.

, INTRODUCTION
Clusters are a collections of atoms or molecules which are intermediate
in size between a molecule and bulk solid. They may have varied
nuclearities and stoichiometry. They can be considered as link between
atoms, molecules and bulk material. The properties of clusters changes
with size. Metal clusters have metal-metal bonds. This chapter first deals
with boron compounds and then gradually leads to clusters such
carboranes, metalloboranes, metallocarboranes and isopoly-heteropoly
acids. These complex materials finds various applications in the
synthesis of various organic derivatives and industry.

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