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Vertiefte Organische Chemie (Lehramt)
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Zusammenfassung/Mitschrift Vertiefte Organische Chemie für Lehramtskandidaten (VOCLA)
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Nucleophile Substitution IIDie Srt -
Reaktion
Sdvdyse von tert BLHYI chlorid
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Kö s II ! Hzö % pH Hi
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H Butanol
planarescarbenilimion
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starkes Elektro phil
entscheidender ReaktionsSchritt monomolekularenuckophile :
Substitution SNI
Charakteristika
mehrstufig Bindungs brach , dann Bindungs bildung
•
:
•
Carbeniumion ER , ist Zwischenstufe ; dessen Bildung ist geschwindigkeitsbestimmend
°
Kinetik erster Ordnung :
KK ,
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ERX ]
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nur ( der Zerfall des ) Elektrophile ist am geschwindigkeits bestimmenden Schritt beteiligt
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Swt führt bei optisch aktiven Edukten zu
Racemisierung >
achiraks Carbeniumion
Energieprofil der Reaktion
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F Carbo kanonische
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Reaktions Koordinate
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