Class notes
Vertiefte Organische Chemie (Lehramt)
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Zusammenfassung/Mitschrift Vertiefte Organische Chemie für Lehramtskandidaten (VOCLA)
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Bindungstypen in organischen VerbindungenEinfach bindungen
gesättigte C- Atome sind solche von denen Einfachbindungen ausgehen
•
,
nur
}
•
gesättigte C- Atome sind sp
-
hybridisiert
Ethan :
H H
>
( ( Sps) -
H ( ts)
\ 1,54 Ä s
H
µ C- ( a-
L I
H H
> ( ( sps ) ( Gps )
MO Diagramm für die C C
Bindung
• -
-
^
E
o; anti bindend >
energetisch stark angehoben
(stärker angehoben also abgesenkt)
i
ÄTZT
- .
Knotenebene ( Wellenfunktion -
- O )
}
sp
}
sp > keine
'
Occ bindend
'
i i
.
C- Atom A
µß C- Atom B
Verbindungsachse
•
Elektronendichte ist rotationssymmetrisch entlang der Kern -
Kern -
Bindung ) > O -
( nahezu frei drehbar
•
Hinzufügen von mehr ( ( sp ' ) -
Atomen zu Ketten und Ringen
>
Stoffklasse der Alkane
, Doppelbindungen
H H
Ethen ist der einfachste Vertreter der Alkene
(
?
1,33 Ä C- Atome sind hybridisiert
>
sp
-
(
H H
Z
i. 9936 gut
×
y
25 2k 2h, Lpz
-
,
mischen lhybridisieren
i. wir gar µ
* är a im
?
sp
-
Hybrid Orbitale :
21oz bleibt übrig
zeigen in die Ecken eines gleichseitigen Dreiecks > IT -
Bindungen
•
MO -
Diagramm
E- ^
OEC
größere Aufspaltung
<
Ffc kleinere Aufspaltung
id
/ <
/
Pz Pz
/ Hetzende ,
T
? cc ?
er
sp
-
sp ^
r Ja
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cc
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Anteil
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