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OCR A Level Chemistry A H432/03 Unified chemistry June 2024 Exam Question paper Authentic Marking Scheme Attached $9.99   Add to cart

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OCR A Level Chemistry A H432/03 Unified chemistry June 2024 Exam Question paper Authentic Marking Scheme Attached

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  • OCR A-LEVEL CHEMISTRY
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  • OCR A-LEVEL CHEMISTRY

OCR A Level Chemistry A H432/03 Unified chemistry June 2024 Exam Question paper Authentic Marking Scheme Attached

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  • May 29, 2024
  • 51
  • 2023/2024
  • Exam (elaborations)
  • Questions & answers
  • OCR A-LEVEL CHEMISTRY
  • OCR A-LEVEL CHEMISTRY
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RevisionKing
Oxford Cambridge and RSA

Thursday 23 June 2022 – Morning
A Level Chemistry A
H432/03 Unified chemistry
Time allowed: 1 hour 30 minutes

You must have:
* 9 1 0 1 4 0 8 2 1 9 *




• the Data Sheet for Chemistry A
You can use:
• a scientific or graphical calculator
• an HB pencil




* H 4 3 2 0 3 *




Please write clearly in black ink. Do not write in the barcodes.

Centre number Candidate number


First name(s)

Last name


INSTRUCTIONS
• Use black ink. You can use an HB pencil, but only for graphs and diagrams.
• Write your answer to each question in the space provided. If you need extra space use
the lined pages at the end of this booklet. The question numbers must be clearly shown.
• Answer all the questions.
• Where appropriate, your answer should be supported with working. Marks might be
given for using a correct method, even if your answer is wrong.

INFORMATION
• The total mark for this paper is 70.
• The marks for each question are shown in brackets [ ].
• Quality of extended response will be assessed in questions marked with an asterisk (*).
• This document has 20 pages.

ADVICE
• Read each question carefully before you start your answer.




© OCR 2022 [601/5255/2] OCR is an exempt Charity
DC (ST/SG) 301078/3 Turn over

, 2
Answer all the questions.

1 These questions are from different areas of chemistry.

(a) Ammonia, NH3, and ammonium nitrate, NH4NO3, are compounds of nitrogen.

(i) The boiling point of NH3 is –33 °C.

The boiling point of NH4NO3 is 210 °C.

Explain why there is a large difference in boiling points.

...........................................................................................................................................

...........................................................................................................................................

...........................................................................................................................................

...........................................................................................................................................

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...................................................................................................................................... [2]

(ii) Two students discuss the oxidation numbers in ammonium nitrate, NH4NO3.

One student claims that the two nitrogen atoms have the same oxidation number. The
other student disagrees and claims that the nitrogen atoms have different oxidation
numbers.

Explain with reasons which student is correct.

...........................................................................................................................................

...........................................................................................................................................

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...................................................................................................................................... [1]




© OCR 2022

, 3
(b) Brass is an alloy of copper and zinc.

The mass spectrum of a sample of brass is shown below.

45.64%




Relative
abundance 20.36%
16.82%

9.53%
6.27%
1.38%
60 61 62 63 64 65 66 67 68 69 70
m/z

The peaks at m/z = 63 and m/z = 65 are from the 63Cu and 65Cu isotopes of copper.

The remaining four peaks are from isotopes of zinc.

(i) What are the percentage compositions of copper and zinc in the brass sample?




Cu = ............. % Zn = ............. % [1]

(ii) Calculate the relative atomic mass of zinc in the sample of brass.

Give your answer to 2 decimal places.




relative atomic mass = .......................................................... [2]




© OCR 2022 Turn over

, 4
(c) The structure of an organic compound is shown below.

The protons are in four different environments, which are labelled 1–4.

2 3
1
CH2 CH2 O
H 3C C C

O H
4

(i) Fill in the table to predict the splitting patterns in the proton NMR spectrum of the
organic compound.

Proton environment Splitting pattern

1


2


3


4

[2]

(ii) The table shows the chemical shifts for the peaks in the proton NMR spectrum at
proton environments 2 and 3.

Proton environment 2 3
Chemical shift, δ 2.5 ppm 3.6 ppm


Suggest why the peaks for proton environments 2 and 3 have the chemical shifts which
are shown in the table.

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...................................................................................................................................... [2]




© OCR 2022

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