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Transition metal Summary note- Chemistry
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Transion MetalDefiritTous :
transiTon
D MeL5lls :
is one thoht formsatbeastome stdsle Tonsu5 thapoirt full-
d
shell
of electrom .
CInterrmofBond) trolsiTonmetlBondedto ans sonads
othe or rsrore
by
in
to - ordimate ,
② corUpIeXTons : AeUtrllToMsUrrOUnded
ordthatelyBonaded Ton Th
YO-
igandson which
的
Co tndiration mhlmrser
-
.
③
aigands: An
atoM, TOnSOrWlECUle WhichCendonateanchector 1 ohe pair .
④ f- ondincitlohhel The
mlber HUM benof
oornateBondkforsued toutrel mhetElLT0 Mon hllmlben
of lecron
:
Pains oncilrd
tr GhoHtn Gtosu .
⑤ Unidesutatte :Ligdoldstholt Can
( Monocdeutate了
only fortssohe fordirate BiAd ,
,
⑥ Bidertate: aigdrads holt coln only foreTwo
o
rdircte Boslal
- ,
⑦ Maltiolentate :
Liglds thatEan
onlyfomheMore theh one0-orlhate BoBd ,
⑧ Redox potetitial : how
easily ions reolueced
is which osthe same ds electrodePotertals
⑨
Autocatabysis .isamother
forslof moogeneoous Catabyss Where the procherct catabysis The eAfon ,
, Properties :
IM terur
4
of
Energyd to explaain . .
9
Puysical
① Cr 订
44
T 1 M
Gonoluctorof heat CH T6 TH Tr I1
→
lectriuty
s ,
T T6
shiMy stronG AhArd betweenthhopatred
→ * decon
,
rephusion ,
igumeltingpoint & Boiling
→
poiont , * more stable to hare unpasred leEtror r
highen
Emergy thanpoatred electom ,
②ChenaiEal
→
fore couplexeb ,
→
foruraloured TOMs ,
forrol vartaable oxidatationstarte ,
Cortllytic activity
→
*
In& sc they tralnsitionhletal
canhot be ,
alur
ays forus fbull
onbitals
they ,
Co ormateBord
-
= Co ordihaateBond
-
=
4 Co orEltnateBord
-
=
6 ,
ugauds 2
igards :
rigdrols 3
: :
4
.
EH2
≈ ~
EHz
L L NHI
→
↓
: ; M ←
M 品 Mits … H
恋
“
ε
z- k 5
“ ^2
CHINH 坐品
_
* the A -
brlEhalTon hllulser arenot
olloadys sarueas
meiberofigolnds
NOTICE :
1
① H20cannot - ordBond, becallselecron cusen
form 2
o
together ,
② ls oMly canform4 o -ordBond,becablse Tonss big
to to
fitTMTONAHSTTTOKMeTL
belris abid ( Tntrceresition whetal 了
.
only found ,
β
LawisAoid: lectoonpairoaccepior ,
←→µƩ L
DwisBase:lectonPaindonom slewis
, sase ,
Ligands
:
② Bicheutohte ③ Miutichentcate
① Monolertaate igGuds
.
ligands .
ligands ,
-
Exuuple : H
2O, } H3 . , Ci NH_ CHECHz {HE ,
[EDTAI4
HIO EBTA :
EbH
Hzo← HzO <↑δ
-
MH 2
→
LToH N iHs CO ( λ41 -
E -
-
K
N
Hz
∅ CH2 -(1+c
crlz ,
0
0 "i ☆ BHz d和 做
( ε
Nlz
然chH
-
% -
εH2 - _
* Comeplex Toiswitthullbtiolenahs ligands=Chelales keylate了 ,
∆、。
。心
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