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CHEM 1001 Chapter 13 14 15 summary notes $13.22
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CHEM 1001 Chapter 13 14 15 summary notes

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An easy to follow and complete summary of the chapters 13 14 15 of the book “Chemistry A Molecular Approach fourth edition”. Notes are written in simple wording, best to review before your exams.

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Chapter 14 Chemical Equilibrium


equilibrium in Hemoglobin


shiftsrightat 02 inlungs
bindingtoHbinlungs
Hb 0 Hbo
releasing02in cells
shiftsleftat 0 intissues


Dynamicequilibrium
a f CB
At start because weonlyhavereactants the rxn onlyshiftsright
As c is beingproducedthe rxn slowsdown 99C suspeed
becausethereverse ran canhappen
After a while the rate oftheforwardran rate ofreverse rxn Dynamiceg'm
Equilibriummeansthat thepartialpressureandconcentration is unchanging
NOT THE AMOUNT
sartialpressureofproducts partialpressureofreactants d rateofforwardrxn.tt rate ofreverseran


0


Even if theamounts aredifferentforeach
their rate isequalandpp and concentration
unchanging I

, Equilibrium constant
aA b I Cccag docag
lag Bag
k
it c the ran order
lawofmassaction
man
a


Equilibrium constantappliesto a systemwhichis chemicallybalanced


concentrations Kc in aqueoussolutions

K
C Dd
Equilibriumconstants a b Neverfor liquidsor
a B

g mn
and
Kp Kp


Relating Kpand Kc
partialpressures in bar are notthe same as concentration in Mol L
BUT
If gasesbehaveideally A
concentration
I
gas law PV nRT P f RT
PAE A RT
A
IF
substitute A in the K equation

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