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DAT General Chemistry exam with complete solutions.

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Atomic Number number of protons found in that atom; low number; (Z) Mass Number Protons + Neutrons; high number; (A) Previous Play Next Rewind 10 seconds Move forward 10 seconds Unmute 0:00 / 0:15 Full screen Brainpower Read More Atomic Mass relative mass of that atom...

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  • August 23, 2024
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DAT General Chemistry exam with
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Atomic Number - ANSWER-number of protons found in that atom; low number; (Z)

Mass Number - ANSWER-Protons + Neutrons; high number; (A)

Atomic Mass - ANSWER-relative mass of that atom compared to the mass of a carbon-
12 atom (which is set at 12.00); measured in amu;

1 amu = - ANSWER-1.66x10^-24

Atomic Weight - ANSWER-weight (g) of one mole (mol) of a given element (g/mol); the
weighted average of all the masses (not the weights) of an element, weighted according
to the natural abundance of the isotopic species of an element

1mol = ______ (Avagadro's Number) - ANSWER-6.022x10^23 molecules

Isotope - ANSWER-multiple species of an atom with same number of protons and a
different number of neutrons (different mass numbers); generally exhibit same chemical
properties

Ernest Rutherford - ANSWER-1911; gave experimental evidence that an atom has a
dense, positively charged nucleus that accounts for a small portion of the volume of the
atom

Max Planck - ANSWER-developed first quantum theory; 1900; proposed that energy
emitted as electromagnetic radiation from matter comes in discrete bundles called
quanta; E=hv (h-Planck's constant)

Planck's constant - ANSWER-6.626x10^-34 J*s

The Bohr Model of the Atom - ANSWER-developed 1913 model of H atom using
Rutherford and Planck's findings; H atom has central proton, electron travels around it in
a circular orbit; centripetal force acting on the electron as it revolved around the nucleus

, was the electrical force between the positively charged proton and negatively charged
electron; quantized angular momentum so it changed in discrete amounts in relation to
the quantum number (L=nh/2pi) n=quantum number h=Planck's constant; from this
Energy of an electron: E=-Rh/n^2, Rh=Rydberg constant 2.18*10^-18 J/electron

Rydberg Constant - ANSWER-2.18 x 10^-18 J/electron

Smaller orbit of electron the... - ANSWER-lower the energy state

What is the Bohr Model used for? - ANSWER-used to explain the atomic emission
spectrum and atomic absorption spectrum of hydrogen; because these spectrum are
not the continuous spectrum that classical physics would expect, they are line spectrum

Balmer Series - ANSWER-4 spectral lines that appear in the visible light region when a
hydrogen atom undergoes a transition from energy levels n>2 to n=2.

Lyman Series - ANSWER-Set of spectral lines appearing in the UV region when a
hydrogen atom undergoes a transition from energy levels n>1 to n=1.

Heisenberg Uncertainty Principle - ANSWER-impossible to determine the momentum
and position of an electron simultaneously; means if the momentum of an electron is
being measured accurately, its position will change and vice-versa

Pauli exclusion principle - ANSWER-no 2 electrons in any given atom can possess the
same set of four quantum numbers (n, l, ml, ms)

Energy state of an electron - ANSWER-the position and energy of an electron described
by its 4 quantum numbers (n, l, ml, ms)

quantum number n - ANSWER-"principal quantum number"; gives info about the size of
the orbital; bigger n is, the bigger the radius of the orbital, the bigger the energy of the
orbital; Max number of electrons in an energy level = 2n^2

quantum number l - ANSWER-"Azimuthal (angular momentum) quantum number";
gives info about the shape of the orbital; value of l = 0 to n-1 ; l=0=s; l =1=p; l=2=d;
l=3=f; Max number of electrons that can exist in a subshell= 4l +2; greater the value of l,
the higher the energy of the subshell, but subshell energies from different principal
energy levels may overlap

quantum number ml - ANSWER-"Magnetic Quantum number"; gives info about the
orientation of an orbital; value of ml = l to -l (includes 0);

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