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A-level CHEMISTRY Paper 2 Organic and Physical Chemistry

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A-level CHEMISTRY Paper 2 Organic and Physical Chemistry Tuesday 18 June 2024 Morning Time allowed: 2 hours Materials For this paper you must have: • the Periodic Table/Data Booklet, provided as an insert (enclosed) • a ruler with millimetre measurements • a scientific calculator, w...

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  • September 11, 2024
  • 40
  • 2024/2025
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Chemistry a level




Please write clearly in block capitals.

Centre Candidate
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Candidate ure
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A-level
CHEMISTRY
Paper 2 Organic and Physical
Chemistry

Tuesday 18 June 2024 Morning Time allowed: 2 hours
Materials
For Examiner’s Use
For this paper you must have:
 the Periodic Table/Data Booklet, provided as an insert (enclosed) Questio Mark
 a ruler with millimetre measurements n
 a scientific calculator, which you are expected to use where appropriate. 1
2
Instructions 3
 Use black ink or black ball-point pen.
4
 Fill in the boxes at the top of this page.
 Answer all questions. 5
 You must answer the questions in the spaces provided. Do not 6
write outside the box around each page or on blank pages. 7
 If you need extra space for your answer(s), use the lined pages at
the end of this book. Write the question number against your 8
answer(s). 9
 All working must be shown. 10
 Do all rough work in this book. Cross through any work you do
11
not want to be marked.
TOTAL
Information
 The marks for questions are shown in brackets.
 The maximum mark for this paper is 105.


Chemistry a level

,Chemistry a level




Chemistry a level

, 2
Do not write
outside the
Answer all questions in the spaces box
provided.


0 1
Propanone reacts with bromine in alkaline conditions.

CH3COCH3 + Br2 + OH– ⟶ CH3COCH2Br + Br – + H2O



The rate equation for this reaction is

Rate = k [CH3COCH3] [OH–]


0 1 .1 Sketch a graph on the axes provided to show how, at constant
temperature, the concentration of bromine changes during this
reaction.
[1 mark]




*02
IB/M/
* Jun24/7405/2

, 3
Do not write
outside the
0 1 .2 Table 1 shows the initial rate of this reaction for experiments using box

different mixtures containing propanone, bromine and hydroxide ions.

Table 1


[CH3COCH3] [Br2] [OH–] Initial rate
Experiment
/ mol dm–3 / mol dm–3 / mol dm–3 / mol dm–3 s–1


1 1.50 × 10–2 2.50 × 10–2 2.50 × 2.75 × 10–11
10–2
2 1.50 × 10–2 2.50 × 10–2 8.25 × 10–11

3 3.75 × 10–3 5.00 × 10–2 1.00 ×
10–1


Complete Table 1.

Use the data from experiment 1 to calculate the rate constant k for

this reaction. Give the units for the rate constant.
[5 marks]




k Units

Question 1 continues on the next page


*03
IB/M/
* Jun24/7405/2

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