BCH exam 2 Questions and Correct Answers the Latest Update and Recommended Version
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Course
BCH
Institution
BCH
Properties of waxes
→ low melting points, stable solids, appear in both plants and animals in nature
→ a wax coat protects the surface of many plant leaves from water loss and attack from
microorganisms
What defines a carbohydrate?
→ aldehydes & ketones with many OH groups, or substanc...
BCH exam 2 Questions and Correct
Answers the Latest Update and
Recommended Version
Properties of waxes
→ low melting points, stable solids, appear in both plants and animals in nature
→ a wax coat protects the surface of many plant leaves from water loss and attack from
microorganisms
What defines a carbohydrate?
→ aldehydes & ketones with many OH groups, or substances that form these when
hydrolyzed
Where do carbohydrates come from?
→ primary products of photosynthesis- extracts carbon from atmosphere and creates
carbs out of that carbon
How are monosaccharides names
→ 1. Based off Aldose or Ketose
→
→ 2. Based off # of Carbons
What is the simplest aldiose and the simplest ketone
Define the D & L stereochemistry of carbohydrates & how it is determined
→ based off glyceraldehyde, CH2OH down in fisher projection
→ - look at side of -OH group
→
→ -OH on right: D- configuration
→ -OH on left L- configuration
→
→ *** OH of highest number Carbon
→ nonsuperimposable mirror images
→ D & L configurations
How many stereoisomers can a molecule have?
→ 2^n where n = # chiral centers
What is a diastereomer?
→ don't differ at ALL chiral carbons, therefore not mirror images
→
→ different physical and chemical properties
What is an epimer? Provide an example
→ 2 sugars that differ only in the configuration around 1 carbon
→
→ galactose and mannose are epimers of glucose
→
→ alpha-D glucose has 3 epimers: B-D-glucose, a-D-mannose, and a-D-galactose
→ D-aldopentoses:
→ 1. D-ribose
→ 2. D-xylose
→
→ What are the 2 D-aldothreoses:
→ 1. D-erythrose
→ 2. D-threose
What defines a disaccharide (upon a hydrolysis run)?
→ forms 2 monosaccharides when hydrolyzed
What defines a polysaccharide?
→ forms many monosaccharides when hydrolyzed
What is a hemiacetal and a hemiketal?
→
What kind of sugars can form rings? What are they called?
→ 5- 6-, and 7- carbon sugars
→
→ Pyranose: 5 members
→ Furanose: 6 members
How are cyclic monosaccharides formed? What arises upon formation?
→ the -OH group on a hexose will attack C-1 to form a ring
→ * the C-1 is the "ball" in the ball and stick models
→
→ when the ring is formed, a new asymmetric carbon is introduced into the molecule
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