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Organic Chemistry (CHEM 343) Exam 2 Summary/Review $8.49
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Organic Chemistry (CHEM 343) Exam 2 Summary/Review

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Complete summary of all reaction mechanisms and lecture materials up to exam 2. Includes examples, stereochemistry, regiochemistry, solvation, charity, and more. Notes color coded and highly organized. This review sheet helped me get an A in the class.

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  • December 21, 2024
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ansems
↑ Fri , ADD'NS OF H-X :
< =
halogen)

1




I and
* attachments of H and Br must be independent

* attachment to more substituted carbon is energetically favored
(regiochem)
* carbocations likely / possible

MKs <p orbital has 2 equal lobes
,
NUC :
can add above or below

-
⑦ plane (stereochem)



↳ ALL ENANTIOMERS



D
8
-
D2
7 RR


ENANTIOMERS
HYDROGENATION


I F , - - -
DIASTEREOMERS
* syn only addition of Hz/D2 (stereochem)
Ph Ph
ph A no carbocations involved (no rearrangements)

ph
I cat H H




X2 ADD'NS
M Br N M

-H
H




# NM
0
:
- H
no skeletal rearrangement no carbocation intermediate


* H20 (nuc) adds to most substituted carbon (regiochem /Mark)

VB :

* nuc adds anti only (stereochem) because LUMO on S+




ongener
* 1st Br attachment controls second add


> larger LuMO lobe
add H20 >
-
alcohol MeoH or EtoH ...
-
ether




HYDROBORATION
#TBT H
-

A EN HY EN B ,
anti markornikov addition (regiochem
-
-
Ov * no intermediate ,
no rearrangement



& 11 .
* syn only addition (stereochem)

I concerted step

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