Summary
samenvatting ALLE reacties organische chemie II (deel 2)
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Een samenvatting/ overzicht van alle reacties en mechanismen gezien in organische chemie II(2e jaar Farmaceutische wetenschappen (2024/2025))
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Full Course Summary Organic Chemistry 1 Bruice
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Ethers R-O-RIH10
Nucleofiele substitutie
doorbraak SN1
etz
CHz-e-ez
enty
+T
c
doorbraak Sn 2
C--chrhrhych
CHICHCHH
EPOXIDEN-c-e-
Nucleofiele substitutie O
i
RCHECHR RIOOH A REACHR RECH
Ring opening d . m v
. . zuur
HBR
02 +
Hal-Cha +
H-Bri Hel-CheiBri DHCheCHaBr
Verdund z u H
-PHE
Chze
-1 tot OH
CHy-CH-eH-tHy CHz-CH-CH -He ↳
CHy-CH-CH-CHz
+
ÖH
zure methand
H-H IB
H H
-PHE ID +
-1
CHy-CH-eH-tHy
OH H
CHz-CH-TH -He ↑
CHzCHCHetz CHzCHCHCHy + HB+
-230H
=
dette
vorming van eis-1 2-dis ,
B
OH
*
1 . OsOn
D
* OH
2 .
HeDz HeD,
areenoxidenomlegging
H10
: -
H
B P
- HB
+
De
leareinogeen
AMINEN B-NHe
CHy CHeBr + CHyNHa dCHzCHaHeCHy +
Br OH
o
-
CHCH-Cha
-02
+ CHyNHabhzCHCHeNHeCHe D CHzCHeHeNHetz
Zuur-gekatalyseerde
amide hydrolyse a
alcoholyse
hydrolyse
eNHCHyCHy Ha CHCH e
alcoholyse 19
-OCHeCHy CHzNHy
Il
-
NHCHyCHytHeOH Me +
6
, (E2)
Hoffmann eliminatie
CHz itz
CHCHNCh Ch =
H + NCH He minder stabiele alkeen gevormd
Ette
Hi ei
base verwijdert Hvid B-2 met de meeste
waterstofatomen
e- O- RI
EStER
R -
!
Zuur
gekatalyseerde ester hydrolyse
Och, He
Het no
Transesterificatie
+ CHzCH20H Hechz +
Ch
ester alcond ester alcond
Aminalyse
mochseheCHNHz
P
1 -
NHCH
TCHzCHgOH
amine amide alcohol
Grighard reagens
15 MgBrt P 101
+ rech R
CHz-Myr &
Chy-MgBr
bret
Additie -
Eliminatie -
additie
Roer H-ÄRCHO-HRCHH
Go
H-NHy
R
a
+
Hot
Claisen condensatie
2
ZHytha-oCHeCHyelo Chgche-en-ochzehchychh
Ete
Gekruisteelaisen condensatie
Chatha-oCHeCHyt OchrCha Chete 2 Hel
add slowly
.
↳ in overmorat
protonen hebben
reagers may geen x
R-C-NGH)-RI
AMIDEN H
In
Reductie LiAlHu
o Alle
*
-TH-Alte
,
O 20 Alte
-
↳ RCHE-CHy DR-CHECHy DR-CHy-Cre
E
amide
R-CHe-NHCHy -H
ondergaan geen nucleofiele
+
additie 7
amine
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