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AQA 7404-2 CHEMISTRTY PAPER 2-AS-MAY 2023-Paper 2 Organic and Physical Chemistry CA$21.46   Add to cart

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AQA 7404-2 CHEMISTRTY PAPER 2-AS-MAY 2023-Paper 2 Organic and Physical Chemistry

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0 1 This question is about the analysis of organic compounds. For each pair of compounds in Questions 01.1 and 01.2, give a reagent (or combination of reagents) that could be added separately to each compound in a single reaction to distinguish between them. State what is observed in each cas...

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  • July 20, 2023
  • 32
  • 2022/2023
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AS
CHEMISTRY
Paper 2 Organic and Physical Chemistry


Tuesday 23 May 2023 Morning Time allowed: 1 hour 30 minutes
Materials For Examiner’s Use
For this paper you must have:
• the Periodic Table/Data Sheet, provided as an insert (enclosed) Question Mark
• a ruler with millimetre measurements 1
• a scientific calculator, which you are expected to use where appropriate.
2

Instructions 3
• Use black ink or black ball-point pen. 4
• Fill in the boxes at the top of this page. 5
• Answer all questions.
• You must answer the questions in the spaces provided. Do not write outside 6
the box around each page or on blank pages. 7
• If you need extra space for your answer(s), use the lined pages at the end of 8
this book. Write the question number against your answer(s).
Section B
• All working must be shown.
• Do all rough work in this book. Cross through any work you do not TOTAL
want to be marked.

Information
• The marks for questions are shown in brackets.
• The maximum mark for this paper is 80.

Advice
You are advised to spend about 65 minutes on Section A and 25 minutes on Section B.



*JUN237404201* IB/M/Jun23/E6 7404/2

, 2
Do not write
outside the
Section A box


Answer all questions in this section.


0 1 This question is about the analysis of organic compounds.

For each pair of compounds in Questions 01.1 and 01.2, give a reagent (or
combination of reagents) that could be added separately to each compound in a
single reaction to distinguish between them.

State what is observed in each case.

0 1 . 1 CH3CH2CH2CHO and CH3CH2CH(OH)CH3
[3 marks]

Reagent(s)

Observation with CH3CH2CH2CHO



Observation with CH3CH2CH(OH)CH3




0 1 . 2 Cyclohexane and cyclohexene
[3 marks]

Reagent(s)

Observation with cyclohexane



Observation with cyclohexene




*02*
IB/M/Jun23/7404/2

, 3
Do not write
outside the
0 1 . 3 Table 1 gives the precise relative molecular masses (Mr) of some organic compounds box

measured using high resolution mass spectrometry.

Table 1

Molecular formula C5H12 C5H10 C6H6
Mr 72.1416 70.1260 to be calculated


Use these data to find the relative atomic masses (Ar) of hydrogen and carbon.
Give your answers to 4 decimal places.

Use these calculated Ar values to find the relative molecular mass (Mr) of C6H6
Give your answer to 4 decimal places.
[3 marks]




Ar of hydrogen




Ar of carbon




Mr of C6H6 9



Turn over ►


*03*
IB/M/Jun23/7404/2

, 4
Do not write
outside the
0 2 This question is about fuels. box



0 2 . 1 Crude oil is separated into fractions by fractional distillation.

State the meaning of the term ‘fraction’ in this context.
[1 mark]




0 2 . 2 Petrol for cars contains branched and cyclic alkanes produced by catalytic cracking.

Identify the catalyst used in this process.
[1 mark]




0 2 . 3 3-Ethyl-4-methylhexane is a branched alkane in petrol.

Draw the skeletal formula of this alkane.
[1 mark]




0 2 . 4 Give the equation for the complete combustion of 3-ethyl-4-methylhexane.
Use the molecular formula for 3-ethyl-4-methylhexane in your equation.
[2 marks]




*04*
IB/M/Jun23/7404/2

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