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Organic Chemistry McMurry CH 17 Practice Exam Questions And Answers Guaranteed Pass.

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Primary Alcohol - correct answer the -OH of alcohol is attached to an end carbon Secondary Alcohol - correct answer An alcohol in which the -OH group is attached to a carbon atom that is attached to two carbon chains and o...

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  • October 9, 2024
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Organic Chemistry McMurry CH 17

Primary Alcohol - correct answer the -OH of alcohol is attached to an end carbon



Secondary Alcohol - correct answer An alcohol in which the -OH group is attached
to a carbon atom that is attached to two carbon chains and one hydrogen atom.



Tertiary Alcohol - correct answer An alcohol in which the -OH group is attached to a
carbon atom that is attached to three carbon atoms and no hydrogen atoms.



How do you name alcohols? - correct answer Parent: Longest chain containing
alcohol

Suffix: -ol

Give lowest possible number to alcohol



What are the properties of alcohol? - correct answer Melting point, boiling point,
and acidity.

More MW = More BP/MP

Branching (same #C's) = Less BP/MP



Rank in order of increasing boiling point:

A. CH3CH3, B. CH3OCH3, C. CH3CH2OH - correct answer A<B<C



Carboxylic Acid - correct answer COOH



Alkyl Halide - correct answer C-X



Ester - correct answer COOR

, Ether - correct answer R-O-R



Alkene - correct answer C=C



Aldehyde - correct answer CHO



Ketone - correct answer RCOR



Hydroboration-Oxidation of Alkene - correct answer 1. BH3 / H2O2

2. OH-

H goes to most substituted C

OH goes to less substituted C



Oxymercuration-Reduction of Alkene - correct answer Converting an alkene to an
alcohol. The alkene is treated with mercury (II) acetate followed by reduction with sodium borohydride

1. Hg(OAc)2, H2O

2. NaBH4

C2 gets OH, C1 gets H.



1) OsO4

2) NaHSO3, H2O - correct answer Syn Dihydroxylation, Treatment with an alkene
gives a syn addition of OH and OH across the alkene



1) RCO3H

2) H3O+ - correct answer Acid-catalyzed Hydrolysis of Epoxide

Anti hydroxylation

adds OH to each double bonded C



1) LiAlH4 or NaBH4

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