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CHAPTER 20—DIENES, CONJUGATED SYSTEMS, AND PERICYCLIC REACTIONS

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CHAPTER 20—DIENES, CONJUGATED SYSTEMS, AND PERICYCLIC REACTIONS MULTIPLE CHOICE 1. Which of the following are conjugated dienes? a. only 1 b. only 2 c. only 1 and 2 d. 1, 2 and 3 ANS: C 2. Which of the following are conjugated dienes? a. only 1 b. only 2 c. only 1 and 2 d. 1, 2 and 3...

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  • August 9, 2021
  • 18
  • 2021/2022
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CHAPTER 20—DIENES, CONJUGATED SYSTEMS, AND PERICYCLIC
REACTIONS


MULTIPLE CHOICE

1. Which of the following are conjugated dienes?




a. only 1
b. only 2
c. only 1 and 2
d. 1, 2 and 3
ANS: C

2. Which of the following are conjugated dienes?




a. only 1
b. only 2
c. only 1 and 2
d. 1, 2 and 3
ANS: B

3. What is the IUPAC name of the following compound?




a. 2,3-dimethyl-2,4-pentadiene
b. (Z)-2,3-dimethyl-2,4-pentadiene
c. 3,4-dimethyl-1,3-pentadiene
d. (Z)-3,4-dimethyl-1,3-pentadiene
ANS: C




BIAF 7e Test Bank

,4. What is the IUPAC name of the following compound?




a. (R)-3-vinyl-1-butene
b. 3-methyl-1,5-pentadiene
c. 3-methyl-1,4-pentadiene
d. (R)-3-methyl-1,4-pentadiene
ANS: C

5. What is the systematic IUPAC name of the following compound?




a. (3S,4E)-3-ethyl-3,4-dimethyl-1,4-hexadiene
b. (3R,4E)-3-ethyl-3,4-dimethyl-1,4-hexadiene
c. (3S,4Z)-3-ethyl-3,4-dimethyl-1,4-hexadiene
d. (3R,4Z)-3-ethyl-3,4-dimethyl-1,4-hexadiene
ANS: A

6. Which of the following alkenes undergoes the least exothermic hydrogenation upon treatment with
H2/Pd




a. 1
b. 2
c. 3
d. 4
ANS: C

7. What is the correct order of exothermicity for hydrogenation of the following hexadienes upon
treatment with H2/Pd (more exothermic > less exothermic)?




BIAF 7e Test Bank

, a. 1>2>3
b. 3>1>2
c. 2>1>3
d. 3>2>1
ANS: B

8. Which of the following arrangements of p atomic orbitals gives the lowest energy -bonding
molecular orbital of 1,3-butadiene?




a. 1
b. 2
c. 3
d. 4
ANS: B

9. Which of the following arrangements of p atomic orbitals gives the highest energy -antibonding
molecular orbital of 1,3-butadiene?




a. 1
b. 2
c. 3
d. 4
ANS: C

10. Which of the following arrangements of p atomic orbitals of 1,3-butadiene has the greatest number of
nodes?




a. 1
b. 2
c. 3
d. 4
ANS: C




BIAF 7e Test Bank

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