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Summary Ieb Energy change and rate of reaction Notes

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Energy changes and graphs and rate of reactions

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  • June 15, 2022
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  • 2021/2022
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Energy changes and Rates of Reactions
Enthalpy (H):

A measure of the internal energy (Ep) of the reactants or products

∆𝐻 = heat of reaction:

The net change of chemical potential energy of the system

Temperature:

The average kinetic energy of the composing particles

When heat is absorbed by a chemical reaction the Ep will increases and the temperature will decrease (Ek decrease)

∆𝐻 > 0
When heat is released by a chemical reaction the temperature will increase (Ek increase) the Ep will decrease

∆𝐻 < 0
∆𝐻 = 𝐻𝑓 − 𝐻𝑖



Exothermic Reaction:

Reactions which transform chemical potential energy into thermal energy ∆𝐻 − 𝑑𝑒𝑐𝑟𝑒𝑎𝑠𝑒𝑠 ∆𝐻 < 0

BOND FORMATION
Energy is released to the surroundings

𝐸𝑐ℎ𝑒𝑚 𝑝𝑜𝑡 → 𝐸𝑘 (thermal disappears)

Releases heat and thus increases the temperature of the reaction mixture



Potential Energy Curve


Activated Complex

H


Ep
(kJ.mol-1) ∆𝐻 = 𝐻𝑓 − 𝐻𝑖

Ea
∆𝐻 < 0
H decreases
Hi Decreases
Reactants potential energy
∆𝐻
therefore
Hf
Products
thermal energy


Progress of reaction
Or
Reaction Pathway

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