Chemical Properties Of Aldehydes And Ketones React
Chemical Properties Of Aldehydes And Ketones React
Chemical properties of Aldehydes and Ketones React
Exam (elaborations)
Chemical properties of Aldehydes and Ketones Reactions common to both Aldehydes and Ket
6 views 0 purchase
Course
Chemical properties of Aldehydes and Ketones React
Institution
Chemical Properties Of Aldehydes And Ketones React
Chemical properties of Aldehydes and Ketones
Reactions common to both Aldehydes and Ketones
The difference between an Aldehyde and a Ketone is the position of the C=O (Carbonyl group).
Aldehyde – always on a carbon at the end of the chain
Ketone – Always on a carbon at middle carbon of the ...
2. BOTH Aldehydes and Ketones undergo nucleophilic substitution using HCN
Def.
A nuclophile is an electron pair donor
E.g. NH3 – 1 lone pair
H2O – 2 lone pairs
OH– – 3 lone pairs
Cl– – 4 lone pairs
Therefore nucleophiles attack
E.g. Cδ+=Oδ– 1
Due to a difference in electronegativity the O is
electronegative than the C so attracts the electron
pair more strongly
, NOTE:
C C – A C=C will undergo
C C = electrophillic addition
reactions and the reagents
are added across the double
bond
– A C=O double bond
undergo nucleophillic
addition reactions and the
C reagents are added across
C O = O
the double bond
Mechanism of the reaction between Ethanal and HCN
Conditions: K+CN– = catalyst
Reagents: O
+ HCN(g)
H3C C H
δ+ O δ+ δ–
H3C C H CN
O H
H
Ethanal Intermediate HC C H
O 3
2 Hydroxylpropanenitrile
N C C CN
H3C H
KCN Nitrile group
CN
Mechanism of the reaction between Propanone and HCN
δ+ δ–
H CN
Conditions: K+CN– = catalyst
Reagents: O
O O H
2
H3C C CH3 HC C CH HC C CH
3 3 3 3
Propanone
CN CN
N C 2 Hydroxyl 2 methylpropanenitrile
Intermediate
KCN
, 3. BOTH react with 2,4, Dinitrophenylhydrazine (2,4, DNPH)
2,4,DNPH is an orange solution
The reaction is used as a test for the C=O double bond
Reacts to give an orange/yellow precipitate
H3C
H2N C N + H2O
HC C O
3
NH H NH
O O
H
Ethanal + +
+
N N
+ O + O
O N O N Orange/Yellow
2,4, DNPH precipitate
O O
Example exam Q.
Q. How can you distinguish between an Aldehyd and a Ketone? (4 marks)
A. Dissolve in 2,4 DNPH if precipitate is found the C=O bond present
Orange precipitate is purified by recrystalisation
Dry the crystals and heat them until their melting point is found
check the melting point found against data
Identify the exact Aldehyde or Ketone found
Reactions for Aldeydes only
1. ONLY Aldeydes can be oxidised with Acidified Dichromate (H+/Cr2O 72-)
Primary Alcohol Aldehyde Carboxylic Acid
Secondary Alcohol Ketone
Tertiary Alcohol
O H O
H3C C + [O] H C C
3
H H OH
H+/Cr2O72-
Ethanal Acidified Dichromate Ethanoic Acid
, 2. ONLY Aldehydes can react in the Silver mirror test (Tollens Test)
Reagents: Silver nitrate dissolved in Amonnia (Ag+ (NH 3)2 )
Conditions: Hot water bath
If an Aldehyde is present the Silver ion (Ag+) changes to a silver atom (Ag)
Ag+ + 1e– Ag(s)
ion – 46e– atom – 47e–
As the Aldehyde was oxidised the Ag+ gained an electron and was reduced
Aldehydes Carboxylic Acid KetonesNo further reaction
4
The benefits of buying summaries with Stuvia:
Guaranteed quality through customer reviews
Stuvia customers have reviewed more than 700,000 summaries. This how you know that you are buying the best documents.
Quick and easy check-out
You can quickly pay through credit card or Stuvia-credit for the summaries. There is no membership needed.
Focus on what matters
Your fellow students write the study notes themselves, which is why the documents are always reliable and up-to-date. This ensures you quickly get to the core!
Frequently asked questions
What do I get when I buy this document?
You get a PDF, available immediately after your purchase. The purchased document is accessible anytime, anywhere and indefinitely through your profile.
Satisfaction guarantee: how does it work?
Our satisfaction guarantee ensures that you always find a study document that suits you well. You fill out a form, and our customer service team takes care of the rest.
Who am I buying these notes from?
Stuvia is a marketplace, so you are not buying this document from us, but from seller fridahmunene626. Stuvia facilitates payment to the seller.
Will I be stuck with a subscription?
No, you only buy these notes for $17.50. You're not tied to anything after your purchase.
