Class notes
Aldhehyde and ketone
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Class short notes by nitesh devnani sir for rapid revision
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Aldehyde Ketones mainn34 Snca
R - C = N --
[H]
nu
at
-
R-G- DEUDE
DE HYDROGENATION =
&
EDUCTION
H2
Carbonyl compounds Dehydration
* of Alcohols Reaction
->
Stephen's
-
· -
(u/A Such
Aldehyde
R-g-R
Ketones alcohol
00 CHy
-
H R R H
-
N
C=
R-G-H Cty-CHG-OH q
-
- -
08
ALDEHYDE HCL
(ul300
(n/300
preparation cr-Its DIBA)
CHPR-CHy
Go alcohol -
H
Aluminium
Di-isobutyl ride
KETONE
Onidation
ofAlcoholsstrong
Ai
SOA ae R- -OR'Y R- -4
c-of(ul300
OA R-COOH
R-CHz
-
OH s alcohol CH -C
Alkene este 8
Reduction
dis
Elimination H -
dis
-
R!
04
+
i alcohol
Mild DIBAL - H
R-CHO HGH
-
R
OA R C N =
WOA
-
Mild
Cyanides
strong or
R CH R
R- Ozonolysis CH3
-
-
i) 03 D
x
OA
da at ETARD
REACTION
H
0
-
= +
CH
*
ETONE
3
00 ii) In (H20
2" alcohol c CH= -
CH3 Reductive (13 ->
cromyl chloride
/ CHy (rOaCle
CHO
Eiseulomonun
R
I strong CH3 CS2
R - C - OH No Run ALDEHYDE CH3 S c S
=
=
OR Mild OA -
i) 03 2 INTERMEDIATE
R ↓
↑OULENE
H-9-cts
c0
=
+ Non Solvent
ii) Hy0 Polar BENZALDEHYDE
G
3' alcohol ACLD KEE
-
Ouidative cry --
↓
Side chain Reaction Cl
Ho--CH3
strong oxidising agent -
ACID
=
is
c/n8
12
e
CH-
I
-
NaOH " -
420
1) KMnOy /Ht 3) (rOz +HSOy Jones
Reagent ag
2 times
2) R2Cr2O7 /Ht 4)
HNO3 Kucherov's Run
SNZ
0H
Hg2+/H
I
Tautomes TOULEME
13
OHS H I
R c
CH2
- =
Weak
Onidising agent R c CH
-
=
-
110
ALKYNE
dilHgsop/bil H2SO4 enol R
- -
CH3
(u/D or
Cul30 or (n573K Nucleophilic Addition Run
Keto
is cla/GY cE"
2) PCC 3]PDC 4) Collin's Reagent
ADDITION
WALER-
OF
Benzoic Acid
Rosenmund's stimes
5) Savett's
Reagent Reaction Acid Halide
ADENIE I
l ↓
AldehydeBason
H2
6) MnOz R
4-
x
R-4
in onWi
-
Acid 46/BaSO4 -- ve catalyst I -
u
1
+2/Pd u
halide
Rosenmund's catalyst Alcohol I
R
&
-
CH-OH
A22L
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