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Alcohol phenol and ether
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Short notes of alcohol phenol and ether for rapid revision
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Alcohol, Phenol , EtherOH
Alcohols 1H20
+
CH3
H I
I R-CH =
CH2 R CH
CH3
- -
of
CH,
CHy-CHz-OH
- y---
CH
-
1o alcohol dis H+
R-CH -
CH
H20
2: alcohol So alcohol
Carbocation
OH
vinylic alcohol x
Electrophilic Addition
CHI = CH -
Rate of a stability of
x
alcohol
CH2CH-cHy-oH allylic
=
Run Carbocation
Benzylic alcohol
CHOH Mercuration)
2) OMDM
(Ony Mercuration De
CH2-OH CH2-OH ) HgCOAC2
OH
tRO
dre-or R
cte
R-CH
CH2
2) CH
- -
=
OH
NaBHn
CH2
=
ethylene glycol dia-or Source ofOH: -
H20
glycerol Source of H:
-NaBHy
PreparationofAlcohols NOTE:
addition
From Alkenes
Addition ofWater
x
Ants
)
Markovnikoy'srule
a) Acidcatalysed hydration > No
rearrangement
Reagent: bil. H2SO4 or HT H20 or Hot > No carbocation
Cyclic
x intermediate
,
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