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Summary Addition Reactions Acids to Alkenes Orgo 1 (Chem 210) Umich $5.00
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  3. University Of Michigan - Ann Arbor
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  5. Chem 210 (CHEM210)

Summary

Summary Addition Reactions Acids to Alkenes Orgo 1 (Chem 210) Umich
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Colorful notes taken on Addition Reactions in Orgo 1 (Chem 210) at the University of Michigan! Outlines concepts from class: addition of strong acids to alkenes, addition of weak acids to alkenes, mechanisms and examples. Great piece of reference material! Intended to be understood in a sho...

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  • September 6, 2024
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.
-.
15
a Addition of Acicl tr
Alkenes-4.5
ACIDSA
STRONG
4.3


Functional Groups and Descriptions
1

unit of structure
that behaves in


predictable ways
Alkyl chunk of
=




c/H sp3

- Cl



butane - -
I

↓_ butene

an alkane alkyl halide
an alkene
C&H sp3 hybridized
haligem in
altare
ca
=

double band


manosubstituted
al
> /
f unsubstituted H CH5
= C -
C
-
alkene
↳ -H Alkene =

H
~ -



4


H CH3 disubstituted
cH] disubstituted
2 ~
CC =
allne ↓
-I cc alllere
CH,
=




symmetrically substituted ~
-

arty unsymmetrically
H
substituted
banded to Ch
(1)
c




de primar ⑭Pl
-
Secondary
alkyl
(27)
halide
bonded to alkyl halide I

I other Carbon bunded to
2 offer



other (wiCl
Tertiary (3)
-
3
C

allyl halice

,- 4.5
as mannere
a
· lie
Let us
elem jeids
addin bo
I
fru
Br m
↳breakab alkenes alkynes
(db(dnd) (trp(bad)

Sorted into two categories
Addition of Acids Addition of weak Acids
Strong
Pka5
&

Bronsted

ina
pibona
Iband e CH3
crs
as a=
HWoz]cata
cre
-
->
=




Lich
= 4
-
CHy
as stand 3
Trisubstitute3
-
disubstituted 1
alcohol
alkene Catalysts alcohol
3 alkyl halice
altere 20 alkyl halide unsymmetrically


3alcohol is
major product,

structural egoisomerformal I alcohol is miner
product
different connectivities that differ

tically in
placement of the Markanikou's Rule -> new H
functional
group
gues
to the end of the it

30 alkyl halide band with the I's
is
major product, 2" alkyl halid most

is mine
product

Mechanism of addition of
strong acids
-

2 step mechanism
1. Protonate it band we most likely strong acid to make a carbocation (Bronstedacid-base reaction
2. Capture carbocation by original conjugate base (lewis)-* oven stell

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