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Summary - org chem 101
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organic chemistry notes about ( aromatic compounds)
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somefactorsofbenzene whenmorethantwosubstituents are presentmolecularformula
cts
a and O and conf for benzene 12,4trimethylbenzene c a 3,5dichlorotowen
on
1 benzenehasacarbonatomsthatarelocatedatthecorners of aregularhexagon
2 inbenzeneone hydrogenatomattachedtoeachcarbon whenbenzeneis considered as a substituent iscalled
3 benzeneisplanar a benzyl byphenyl al benzene
4 all ofthecarbon carbonbondlength are identical 139A
5 benzenedoesn'tundergoadditionreaction itreactsmainlysubstitution O phenylcyclopropane or cyanpropylbenzene
6 all sixhydrogeninbenzene arechemicallyequivalent
20
g
inbenzene theelectrons are distributedevenlyaroundthering
8 inbenzene eachcarbon is sp hybridized O j o
no
9 there are sixpielectron in benzene g pm Mnitrobenzylalcohol
Nomenclature of aromaticcompound Reaction of aromaticcompounds
at's on coot notes reactionsofalkane is substationreaction
O O O ga O reactionsofalkene alkyne isadditionreaction
benzene benzene toluene phenol's aniline benzoicacid reactionsofaromaticcompound iselectrophilicaromaticsubstation
Én arctic o ans I ans Br
O O O O O
acetophenonetchorobinzene O Halogenation reactionwithhalogen
benzaldehyde styrene anisole benzene
bromo a chlorination
oh t's O dz facts O Hel chlorobenzene
g sgt's gosh goat's get b bromination
nitrobenzene sulfonic
cumene benzene
acid'ethylbeneene
benzene
propyl O BraFebus O I Her bromobenzene
when two substituents arepresent O t Hcl
1,2 ortho 1,3 meta 1,4 para a 1,2 dichlorobenzen b chlorobenzene c p chlorobenzen
j a
dibromobene
Nitration Noa
2504
1,2 di chlorobenzene
Iupac 1,3 dibromobenzene Iupac O two O H2o nitrobenzene
o dichlorobenzene common m common
sulfonation 5034
q O so masoy
O
son
H2o sulfonicacid
benzene
gg
1,2 dimethylbenzene Iupac 1,4 dimethylbenzene tupac I noonzoonphenol
n p xylene common O 1 so nason
a naanzoo asbenzenesulfonicacid
so H b phenol c nitrobenzene
a chlorobenzenesulfonicacid Iupac
O
a P chlorobenzenesulfonicacid common friedal crafts alkylation
on
O R O HR
O a
g w
chitti
ft O
alky
case Alas O
et's
tic toluene
M chlorophenol M Nitrotoluene o ethylaniline
that's
O chaotic Alas o Hci ethylbenzene
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