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Coordination Chemistry
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, 1Chlorophyll Mg Complex
. :
Haemoglobin
:
Fe Complex
Vitamin Biz :
Co Complex
.
2
Secondary Valence : No · of
groups bound
directly to metal ion
.
3
Primary valance : Ionisable a satisfied by negative ions
Seconday valance :· non-ionisabled satisfied by neutral a
negative ions
Sec Valance is coordination number
equal to
·
+
5 Octahedral : [Colwig), 3t ,
[CoC (wighj &
[CoP(NH3)]
~
↳Tetrahedral i a garde
i
3
.
5 Carnallite MgC GHO
-
KCI .
·
Double Salt
Mohr's Salt-FeSon (NM) Son GH0 · :
<
Potash alum -
Kan
(Son) ·
1240
i
.
6 Central atoms
Teraak
act as Lewis acid because
they accept election .
T
muchs
Protein
nee
.
7 Can act as
ligand
8 Didentate : ethanes ,
2 diamine (MINCHINH2) or
Coloxalate)
Hexadentale :
Ethylenediamine Ketraacetate ior (EDTA4-) (Bind through 2-NEG-0)
. When
9 a Di or
polydentale ligand uses 2 or more to bind Simultaneously
then it is chelate
called
ligand .
10
. Chelate forms
ligand Chelate complex which are more stable
.
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