Chemistry
Advanced Subsidiary
PAPER 2: Core Organic and Physical Chemistry
Marks
Pearson Edexcel Level 3 GCE CHEMISTRY Advanced Subsidiary PAPER 2: Core Organic and
Physical Chemistry QP MAY 2024
Instructions
• Use
•Fill inIfblack ink or ball‑point pen.
• centre number
pencil is used for diagrams/sketches/graphs it must be dark (HB or B).
the boxes at the top of this page with your name,
and candidate number.
• Answer all questions.
• Answer the questions in the spaces provided –
there may be more space than you need.
Information
• The
• The
total mark for this paper is 80.
marks for each question are shown in brackets
– use this as a guide as to how much time to spend on each question.
• For the question marked with an asterisk (*), marks will be awarded for your ability to structure
your answer logically, showing the points that you make are related or follow on from each
•
other where appropriate.
A Periodic Table is printed on the back cover of this paper.
Advice
• Read
• your answers
each question carefully before you start to answer it.
•
Show all your working in calculations and include units where appropriate. Check
if you have time at the end.
Turn over
Some questions must be answered with a cross in a box . If you change your mind about an
DO NOT WRITE IN THIS AREA
answer, put a line through the box and then mark your new answer with a cross .
1 The relative molecular mass of a solid dicarboxylic acid, HOOC(CH2)nCOOH, can be
found using a titration. The acid, which can be represented as H2A, was dissolved in
deionised water and the solution made up to 250 cm3.
(a) Which piece of apparatus should be used for making a solution with a volume of exactly
250 cm3 ?
(1)
A burette
B measuring cylinder
C pipette
D volumetric flask
DO NOT WRITE IN THIS AREA
(b) A solution of 0.100 mol dm–3 sodium hydroxide solution was added to a burette. A
rough titration was carried out on a 25.0 cm3 portion of the acid solution.
(i) The diagram shows the burette before the rough titration. What
is the initial burette reading for this titration?
(1)
2.0
3.0
DO NOT WRITE IN THIS AREA
A 2.40 cm3
B 2.45 cm3
C 3.55 cm3
D 3.60 cm3
2
■■■■
, (ii) The final burette reading for the rough titration was 26.50 cm3.
Calculate the volume of sodium hydroxide solution added in the rough
DO NOT WRITE IN THIS AREA
titration, using your answer to (b)(i).
(1)
(iii) Describe how you would use the rough titration value when carrying out the
accurate titrations.
(1)
............................................................................................................................. .. ............................................................................................................................. .. ......................
DO NOT WRITE IN THIS AREA
............................................................................................................................. .. ........................................... .................................................................................... ......................
DO NOT WRITE IN THIS AREA
3
■■■■ Turn over
, (c) 25.0 cm3 portions of the acid solution were titrated with
0.100 mol dm–3 sodium hydroxide solution.
DO NOT WRITE IN THIS AREA
The equation for the reaction is shown.
H2A(aq) + 2NaOH(aq) Na2A(aq) + 2H2O(l)
The acid solution was pipetted into a conical flask and titrated. The
accurate titrations were carried out three times.
The following results were recorded for the accurate titrations.
Titration number 1 2 3
Burette reading (final) / cm3 47.80 24.35 47.60
Burette reading (initial) / cm3 24.50 1.00 24.35
Volume of NaOH used / cm3 23.30 23.35 23.25
DO NOT WRITE IN THIS AREA
(i) Calculate the mean titre for these accurate titrations. (1)
(ii) Calculate the number of moles of sodium hydroxide in the mean titre. (1)
DO NOT WRITE IN THIS AREA
4
■■■■
The benefits of buying summaries with Stuvia:
Guaranteed quality through customer reviews
Stuvia customers have reviewed more than 700,000 summaries. This how you know that you are buying the best documents.
Quick and easy check-out
You can quickly pay through credit card or Stuvia-credit for the summaries. There is no membership needed.
Focus on what matters
Your fellow students write the study notes themselves, which is why the documents are always reliable and up-to-date. This ensures you quickly get to the core!
Frequently asked questions
What do I get when I buy this document?
You get a PDF, available immediately after your purchase. The purchased document is accessible anytime, anywhere and indefinitely through your profile.
Satisfaction guarantee: how does it work?
Our satisfaction guarantee ensures that you always find a study document that suits you well. You fill out a form, and our customer service team takes care of the rest.
Who am I buying these notes from?
Stuvia is a marketplace, so you are not buying this document from us, but from seller papersbybree. Stuvia facilitates payment to the seller.
Will I be stuck with a subscription?
No, you only buy these notes for $12.99. You're not tied to anything after your purchase.