CHEM 121 FINAL EXAM | UPDATED QUESTIONS AND
ANSWERS UPDATED .Buy Quality Materials!
number of pairs: 2
linear, 180', sp hybridization, nonpolar
drawing: linear
number of pairs: 3
3 bonded, 0 lone: trigonal planar, 120', sp^2 hybridization, nonpolar
2 bonded, 1 lone: Bent/V-shaped, 104.5', sp^2 hybridization, polar
drawing: trigonal planar
number of pairs: 4
4 bonded, 0 lone: tetrahedral, 109.5', sp^3 hybridization, nonpolar
3 bonded, 1 lone: trigonal pyramidal, 107', sp^3, polar
2 bonded, 2 lone: bent/v-shaped, 104.5', sp^3, polar
drawing: tetrahedral
number of pairs: 5
5 bonded, 0 lone: Trigonal bipyramidal, 90' and 120' and 180', sp^3d hybridization,
nonpolar
4 bonded, 1 lone: see-saw, 90' and 120' and 180', sp^3d, polar
3 bonded, 2 lone: T-shaped, 90' and 180', sp^3d, polar
2 bonded, 3 lone: linear, 180', sp^3d, nonpolar
drawing: trigonal pyramidal
number of pairs: 6
6 bonded, 0 lone: octahedral, 90' and 180', sp^3d^2 hybridization, nonpolar
5 bonded, 1 lone: square pyramidal, 90' and 180', sp^3d^2, polar
4 bonded, 2 lone: square planar, 90' and 180', sp^3d^2, nonpolar
drawing: bent
drawing: trigonal bipyramidal
drawing: octahedral
Determining formal charge rules
Formal charge= (# valence e-'s neutral atom) - (# valence e-'s on atom in structure)
LE model tricks
1. Organic mole can never have lone pairs
2. F never forms multiple bonds and Be and B (and B group) like to be electron deficient
3. Atoms in third row and larger can exceed octet
3. If formal charge isn't 0 then the most electronegative atom gets the negative charge
MO order for group 2 elements
Sigma 2s, sigma 2s, pi 2p, sigma 2p, pi 2p, sigma 2p*
For O2 and F2 only: sigma 2s, sigma 2s, sigma 2p, pi 2p, pi 2p, sigma 2p*
Quirks: for heteronuclear diatomic molc. assume orbitals from less electronegative atom
B2 MO's
paramagnetic, bond order=1 cations become smaller
C2 MO's
diamagnetic , bond order=2 cations become smaller
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