Chem 210 exam 3 stuvia - Study guides, Class notes & Summaries

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what factors explain the outcomes of reactions? - ANSWERhybridization, delocalization, eN, atom density what is a leaving group? - ANSWER- group of atom(s) that can be stable on its own - eN atoms that are good LG also make strong acids what is the α carbon? - ANSWERC directly attached to leaving group what are β Cs? β Hs? - ANSWERβC: C(s) attached to α carbon βH: H(s) attached to βC what is a LB? is it a nucleophile or electrophile? - ANSWERlewis base, nucleophile what i...

less - ANSWERthe more s character a carbocation has, the _____stable it is the same as - ANSWERwhen looking at an epoxide, the orientation around the oxygen is _________ the orientation around the double bond in the reactant BrOH - ANSWERwhen added with base makes an epoxide Br2 - ANSWERadds 2 Brs in anti conformation lindlar catalyst - ANSWERproduces a Z alkene from an alkyne (adds 2 Hs in syn) add more electronegative atom, add pi bond - ANSWER2 ways of producing an oxidation re...

SN1 Reaction - ANSWER- Unimolecular nucleophilic substitution - 2 steps - Starting with enantiomerically pure product tends to result in some degree of racemization - Retention AND inversion at stereocenter (R and S) - 1 nucleophile is replaced by another nucleophile - Carbocation INTERMEDIATE forms - Rate is dependent only on substrate concentration 1. LG leaves, forming a carbocation 2. Nucleophile attacks the carbocation, forming the product SN2 Reaction - ANSWER- Bimolecular nuc...

H-X CCl4 - ANSWERADD STRONG ACIDS, -hydrohalogens - Mark w H-shift + cat. (X= Cl, Br, I) SYN+ANTI H2O H2SO4 - ANSWERADD WEAK ACIDS, -hydration -Mark SYN + ANI Cl2, Br2, I2 CCl4 - ANSWERADD X2 (Cl, Br, I), halogenation ANTI Cl2, Br2, I2 H2O / R-OH - ANSWERADD halogen and OH halohydrin ANTI 1) NCS, NBS, NIS 2) H2O / R-OH - ANSWERADD halogen and OH halohydrin ANTI H-OX/ R-OX (X=Cl, Br, I) - ANSWERADD halogen (X) and OH halohydrin ANTI 1) BH3 2) NaOH, H2...

Acid - ANSWERa substance that has H+ in its formula and dissociates in water to yield H3O+ -some strong acids are HCl, HI, CHlO4, HBr, H2SO4 and HNO3 -loses proton; forms conjugate base (OH- , hydroxide ion) Base - ANSWERa substance that has OH in its formula and dissociates in water to yield OH- -strong bases include NaOH, KOH, and Ba(OH)2 -a strong base will have OH in its formula -gains proton; forms conjugate acid (H3O+ , hydronium ion) Salt and water are the products in reactions...

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