Stereochemistry 1 Study guides, Class notes & Summaries

Basicity rules - -strong base: unstable/reactive (ED groups) -weak base: stable (EW groups/more EN/bigger) Chair conformation - -more stable equitorial (slanted) -pointing up/pointing down=cis if both up -elimination: trans and diaxial Newman projection - -gauche: substituent groups adjacent to eachother -grab middle and turn to put in plane Enantiomers - -not superimposable mirror images -same besides stereochemistry Diastereomers - -mirror images but one stereocenter stays and...

MCAT AAMC FL 1EXAM QUESTIONS AND ANSWERS What was the principal factor determining the migration of individual components in a sample when performing chromatography? -Answer-the relative amount of hydrogen bonding to the stationary phase Rf value -Answer-Distance travelled by substance / distance travelled by solvent stereospecific reaction -Answer-a special type of stereoselective reaction in which the stereochemistry of the product is dependent on the stereochemistry of the starting mate...

IR Spectra correct answer: -Absorption of radiation causes vibrational excitation of functional groups *making it easy to ID functional groups* *0-5000cm-1* H NMR Spectra correct answer: *0-12ppm* C NMR Spectra correct answer: *0-200ppm* Mass Spec correct answer: -Used to measure the molecular weight (mass) of the compound. Alkyne Reactions correct answer: *1* Alkyne + H2/Pd &C = Alkene *2* Alkyne + H2/Lindlav Cat.= Cis Alkene *3* Alkyne + Li or Na/Liquid NH3= Trans Alkene ...

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strong base, weak nucleophile correct answer: NaH strong base, weak nucleophile correct answer: DBN strong base, weak nucleophile correct answer: DBU strong base, strong nucleophile correct answer: HO- strong base, strong nucleophile correct answer: MeO- strong base, strong nucleophile correct answer: EtO- weak base, strong nucleophile correct answer: I- weak base, strong nucleophile correct answer: Br- weak base, strong nucleophile correct answer: Cl- weak ba...

temperature is related to KE how? temp is the average kinetic energy thermal energy is related to KE how? thermal energy is the total KE Brainpower enthalpy of fusion is ALWAYS greater than enthalpy of vaporization because? it has to break more bonds (solid --> liquid) the amount of heat depends on (2 factors) 1. the type of substance 2. the amount of the substance during a phase change does temperature change? NO if an archaebacerial species lives in a pool that is 0.01 M HCL wh...

Chapter 1 Carbon and Its Compounds CHECKPOINT PROBLEMS Practice Problem 1.1 a) S — 1s2 2s2 2p6 3s2 3p4 b) Cl — 1s2 2s2 2p6 3s2 3p5 c) Na+ — 1s2 2s2 2p6 1-2 Copyright © 2018 Nelson Education Limited Practice Problem 1.2 a) Count valence electrons. Build a basic bonding framework and account for electrons used. Add remaining electrons and check for formal charges. The molecule has a lone pair on the nitrogen. All other electrons are bonding electrons. b) Count valence electrons. Build a bas...

Chapter 1—Structure and Bonding SHORT ANSWER 1. Give the ground-state electron configuration for carbon (atomic number 6). ANS: 1s22s22px12py1 or 1s22s22p2 2. Give the ground-state electron configuration for fluorine (atomic number 9). ANS: 1s22s22px2 2py2 2pz1 or 1s22s22p5 3.Give the ground-state electron configuration for magnesium (atomic number 12). ANS: 1s22s22p63s2 4. How many electrons does silicon have in its valence shell? ANS: four Exhibit 1-1 Write valid Lewis (electron-...

1 MODULE 8 PORTAGE 219 ORGANIC CHEMISTRY EXAM | QUESTIONS & ANSWERS (VERIFIED) | LATEST UPDATE | GRADED A+ large molecule made by repetitive linking of smaller units (monomers) Correct Answer: Polymer very large molecule composed of thousands of covalently bonded atoms (ex: polymer) Correct Answer: Macromolecule two ways polymers are made Correct Answer: 1. natural (in nature) 2. synthetic (in lab) natural polymers Correct Answer: rubber, carbs: starch & cellulose, proteins, nu...