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Organic chemistry, Thermodynamics, Enthalpy, Reaction, Entropy, Difficulty level, nucleophilic attack

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Organic chemistry, Thermodynamics, Enthalpy, Reaction, Entropy, Difficulty level, nucleophilic attack

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  • 6 de diciembre de 2021
  • 34
  • 2021/2022
  • Examen
  • Preguntas y respuestas
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Chapter 6

Topic: Enthalpy
Section 6.1
Difficulty Level: Medium

1. Estimate the enthalpy change of the following reaction under standard conditions.

Ans: +8 kJ/mol

Topic: Enthalpy
Section 6.1
Difficulty Level: Medium

2. Estimate the enthalpy change of the following reaction under standard conditions.


Ans: +29 kJ/mol

Topic: Enthalpy
Section 6.1
Difficulty Level: Medium

3. Estimate the enthalpy change of the following reaction under standard conditions.


Ans: -8 kJ/mol

Topic: Enthalpy
Section 6.1
Difficulty Level: Easy

4. Which of the following is the enthalpy change of the following reaction under
standard conditions?

A. -8 kJ/mol
B. +8 kJ/mol
C. +222 kJ/mol
D. +79 kJ/mol
Ans: B

Topic: Enthalpy
Section 6.1
Difficulty Level: Medium

, 5. Which of the following is the enthalpy change of the following reaction under
standard conditions?


A. -8 kJ/mol
B. +8 kJ/mol
C. -506 kJ/mol
D. +63 kJ/mol
Ans: A

Topic: Enthalpy
Section 6.1
Difficulty Level: Medium

6. Later in the course, we will compare the halogenation of differently substituted
carbons, comparing reactions like the ones below. Which of the following
statements is true about reactions A and B?




A. Both reactions have a positive heat of reaction (Ho)
B. Neither reaction has a positive heat of reaction (Ho)
C. Only reaction A has a positive heat of reaction (Ho)
D. Only reaction B has a positive heat of reaction (Ho)
Ans: B

Topic: Enthalpy
Section 6.1
Difficulty Level: Medium

7. Later in the course, we will compare the halogenation of differently substituted
carbons, comparing reactions like the ones below. Which of the following
reactions has a more exothermic heat of reaction (Ho)?




A. Reaction A has a more exothermic heat of reaction (Ho)
B. Reaction B has a more exothermic heat of reaction (Ho)
C. Both reactions have the same heat of reaction (Ho)
Ans: B

,Topic: Enthalpy
Section 6.1
Difficulty Level: Hard

8. You are working in a research laboratory and have developed a new reagent that
cleaves C-H bonds homolytically. Unfortunately, this reagent can achieve only one
of the transformations shown below. In light of bond dissociation energies, which
transformation is most likely to be achieved?




Ans: A

Topic: Enthalpy
Section 6.1
Difficulty Level: Easy

9. What type of bond cleavage does the following reaction involve?

A. homolytic
B. heterolytic
Ans: A

Topic: Enthalpy
Section 6.1
Difficulty Level: Easy

10. What type of bond cleavage does the following reaction involve?


Ans: heterolytic

Topic: Entropy
Section 6.2
Difficulty Level: Easy

11. Predict the sign of S of the following reaction.

, A. positive
B. negative
C. no change
Ans: B

Topic: Entropy
Section 6.2
Difficulty Level: Easy

12. Predict the sign of S of the following reaction.


A. positive
B. negative
C. no change
Ans: A

Topic: Entropy
Section 6.2
Difficulty Level: Easy

13. Predict the sign of S of the following reaction.


A. positive
B. negative
C. no change
Ans: B

Topic: Entropy
Section 6.2
Difficulty Level: Medium

14. Predict the sign of S of the following reaction.


Ans: positive

Topic: Entropy
Section 6.2
Difficulty Level: Medium

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