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Final Inorgo Exam Questions And Complete Correct Answers Graded A+.

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  • NA 701
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  • NA 701

Consider ionic compound, MX3, composed of generic metal M and generic gaseous halogen X. Enthalpy of formation of MX3 =-701kJ/mol enthalpy of sublimation of M= 177 kJ/mol 1st, 2nd, and 3rd ionization energies of M=625 kJ/mol, 1583 kJ/mol, and 2469 kJ/mol Electron affinity of X =-315kJ/mol...

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  • 20 de agosto de 2024
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  • NA 701
  • NA 701
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Final Inorgo

Consider ionic compound, MX3, composed of generic metal M and generic gaseous halogen X.

Enthalpy of formation of MX3 =-701kJ/mol



enthalpy of sublimation of M= 177 kJ/mol



1st, 2nd, and 3rd ionization energies of M=625 kJ/mol, 1583 kJ/mol, and 2469 kJ/mol



Electron affinity of X =-315kJ/mol



bond energy of X2= 183kJ/mol



Determine the lattice energy of MX3 - correct answer lattice energy = -4885
kJ/mol

enthalpy of sublimation is -701

bond energy is 3/2BE= (3/2)(183)



add ionization energies



electron affinity= 3EA= (3)(-315)



H lattice= H formation-( H sublimation + BE + IE + EA)

= -701- [(177) + 3/2(183) + (625) + (1583) + (2469) - 3(315)

= -4885



What is the ground state electron configuration for C+2? bond order? - correct answer
ground state e- config:

,(σ1s)^2 (σ1s*)^2 (σ2s)^2 (σ2s*)^2 (π2p)^3



bond order= 1.5

Bond order= (bonding e-)- (antibonding e- *)/ 2

= (7-4)/2= 3/2=1.5



classify as polar or nonpolar - correct answer Polar: SO2, SF4

Nonpolar: BCl3



Determine the point group of the molecule shown. SF6 - correct answer Oh



Sodium lauryl sulfate is used in shampoos and cleansers. The structure is shown . Which atom in sodium
lauryl sulfate has an expanded octet? In which period is the atom with the expanded octet? How many
electrons are in the valence energy level of the atom with the expanded octet? - correct answer
sulfur

period 3

12 electrons



arrange the metals according to their densities. Based on the trend where would you expect the density
of Zn to be ranked? Where is the density of Zn actually ranked? - correct answer
Most dense

Fe

Mn

Cr

V

Ti

Least dense



More dense than Fe

, Somewhere in between Ti and Fe



The radius of a single atom of a generic element X is 133 picometers (pm) and a crystal of X has a unit
cell that is body- centered cubic. Calculate the volume of the unit cell. - correct answer
2.90 x 10^-29



Determine the point group of the molecule: PF2Cl3 - correct answer D3h



Calculate the enthalpies of formation of group 1 chloride compounds from the Born-Haber cycle. -
correct answer Sublimation of Na(s)= 108

Sublimation of Rb(s)= 86

Dissociation of Cl2(g)= 244 (divide by 2 so 122)

Ionizatinon energy of Na(g)= 496

Ionization energy of Rb(g)= 403

Electron affinify of Cl(g)=-349

Lattice enthalpy of NaCl(s)=787

Lattice enthalpy of RbCl(s)=695



Enthalpy of formation of NaCl= -410 kJ/mol

Enthalpy of formation of RbCl=-433 kJ/mol



Add together.



Give the highest oxidation state for Sc - correct answer +3 (equal to its charge)



identify the packing in the unit cell of the ionic crystals shown - correct answer
cube with one gray ball inside is simple (primitive) cubic

cube with gray balls all over is it face-centered

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