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Practice Questions for Organic Chemistry 2 (Robinson's annulation, Mannich Reaction, etc.)
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What are the limitations of using Grignard's reagent in a reaction?
What are the limitations of using Grignard's reagent in a reaction?
- No water or acidic protons can be in the substrate (OH-, NH-, SH-, etc.)
- No electrophilic/multiple bonds (This causes Grignard's to attack both carbonyl carbons) (N2,NO, SO, CN)
-Grignard's will attack twice if the reaction has acid halides and esters.
In catalytic hydrogenation, if you want to reduce only the double bond and not a carbonyl group what is the best reagent to use?
In catalytic hydrogenation, if you want to reduce only the double bond and not a carbonyl group what...
H2 Pd-c
When reacting a carbonyl group with an amide group, which Amide derivative cannot maintain a double bond attached to it?
When reacting a carbonyl group with an amide group, which Amide derivative cannot maintain a double ...
Enamine
(Enamines form when an amide is di-substituted and cannot hold the charge so there is a bond shift)
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