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Test Bank for Organic Chemistry 9th Edition Wade / All Chapters 1 - 26 / Full Complete
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1 Copyright © 201 7 Pearson Education, Inc. Organic Chemistry, 9e (Wade) Chapter 1 Structure and Bonding 1) While you were up late one night studying organic chemistry, you happened to see the last 5 minutes of an infomercial on TV. The spokesperson claimed that their brand of automobile tires were superior to all other brands on the market because they were made by using only natural rubber, isolated from the resin of rubber trees. How could a chemist test her claims that no petroleum products went into the manufacture of her brand of tires? Answ er: Compounds synthesized from petroleum products have a lower content of Plant -derived compounds are recently synthesized from CO 2 in the air and have a higher content. Diff: 2 Section: 1.1 GO: G5 2) The atomic number of boron is 5. The correct el ectronic configuration of boron is: A) 1s 22s3 B) 1s 22p3 C) 1s 22s22p1 D) 2s 22p3 E) 1s 22s23s1 Answer: C Diff: 1 Section: 1.2 LO: 1.1 3) How many distinct p orbitals exist in the second electron shell, where n = 2? A) 2 B) 3 C) 4 D) 5 E) 6 Answer: B Diff: 1 Section: 1.2 4) The ________ tells us that each orbital can hold a maximum of 2 electrons. A) aufbau principle B) Pauli exclusion principle C) Hund's rule principle D) LeChatelier principle E) uncertainty principle Answer: B Diff: 1 Section: 1.2 2 Copyright © 201 7 Pearson Education, Inc. 5) A node is a region of high electron density between the two atoms in a covalent bond. Answer: FALSE Diff: 1 Section: 1.2 6) When filling two or more orbitals of the same energy with electrons, the electrons will go into different orbitals rather than pair up in the same orbital. Answer: TRUE Diff: 1 Section: 1.2 7) Atoms with the same number of protons but different numbers of neutrons are called ________. Answer: isotopes Diff: 1 Section: 1.2 GO: G2 8) The electron density of ________ orbitals has spherical symmetry. Answer: s Diff: 1 Section: 1.2 9) The formal charge on the nitrogen on the structure shown below is: Answer: N = +1 Diff: 1 Section: 1.7 LO: 1.3 GO: G2 MCAT LO: MCAT1.2 10) An oxygen atom has ________ valence electrons. Answer: 6 Diff: 1 Section: 1.2 LO: 1.1 11) Which element in the second row of the periodic table has six valence electrons and a valence of two? Answer: oxygen Diff: 1 Section: 1.2 LO: 1.1 3 Copyright © 201 7 Pearson Education, Inc. 12) Orbitals which are equal in energy are referred to as __ ______. A) degenerate B) polar C) nodes D) filled E) nonpolar Answer: A Diff: 2 Section: 1.2 13) In a carbon atom, the 2s and 2p orbitals are the same energy. Answer: FALSE Diff: 2 Section: 1.2 LO: 1.1 14) The element with the electronic configuratio n 1s22s22p63s1 is ________. Answer: sodium Diff: 2 Section: 1.2 LO: 1.1 15) Provide the electron configuration of phosphorus. Answer: 1s 22s22p63s23p3 Diff: 2 Section: 1.2 LO: 1.1 16) Draw the shape of a 2p orbital, including shading to indicate pha se. Answer: Diff: 2 Section: 1.2 17) Draw a correct Lewis structure for chloromethane, CH 3Cl, including all non -bonding lone pairs. Answer: Diff: 1 Section: 1.4 LO: 1.3 MCAT LO: MCAT1.2 4 Copyright © 201 7 Pearson Education, Inc. 18) Provide a Lewis structure for a molecule with molecu lar formula CH 2O2. Answer: Diff: 2 Section: 1.4 LO: 1.2 GO: G2 MCAT LO: MCAT11.2 19) Draw the Lewis structure for 2 -propanol, CH 3CH(OH)CH 3, including all non -bonding lone pairs. Answer: Diff: 2 Section: 1.4 LO: 1.3 MCAT LO: MCAT1.2 20) Draw the Lewis structure of acetic acid, CH 3CO2H, including all non -bonding lone pairs. Answer: Diff: 2 Section: 1.4 LO: 1.3 MCAT LO: MCAT1.2
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