ACS Organic Chemistry (ACS)

Organic Chemistry ACS Final Exam Questions With Correct Verified Solutions A+ Graded Basicity rules - ANS -strong base: unstable/reactive (ED groups) -weak base: stable (EW groups/more EN/bigger) Chair conformation - ANS -more stable equatorial (slanted) -pointing up/pointing down=cis if both up -elimination: trans and diaxial Newman projection - ANS -gauche: substituent groups adjacent to each other -grab middle and turn to put in plane Enantiomers - ANS -not superimpos...

Organic Chemistry ACS Final Exam Questions And Answers All Verified By An Expert A+ Graded ketone aldehyde carboxylic acid ester

C C A D B D B A C A B

What is the general formula for a carbohydrate? - Cx(H2O)y How do you determine the number of stereoisomers for a given carbohydrate? - 2^n where n= number of stereocenters Distinguish between the D and L designations for carbohydrates. - In the L form the hydroxy group is on the bottom left closest to the CH2OH group in the frame of a Fischer projection In the D form the OH is on the bottom right What are anomers? - Diastereomers formed by the cyclization of carbohydrates (*note they ...

Functional group: alkane Functional group: alkene Functional group: alkyne Functional group: benzene ring (phenyl) Functional group: amine Functional group: alcohol Functional group: ether Functional group: alkyl halide Functional group: thiol Functional group: aldehyde Functional group: ketone Functional group: ester

-al -ol or hydroxy- -one -oic acid -oate -ether or alkoxy- Iodo- or Bromo- etc. -amide Amino- or -amine - Aldehyde Alcohol Ketone Carboxylic acid Ester Ether Alkyl halides Amide Amine Constitutional Isomer - A compound with the same atoms but different atoms bonded to each other Stereoisomers - Molecules with the same atoms differing only in 3D configuration Enantiomers - Stereoisomers with exactly opposite stereochemical designations at all stereogenic carbons Dia...

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