Electrophilic - Study guides, Class notes & Summaries

Carboxylic acid derivatives undergo _______ reactions A. nucleophilic substitution B. nucleophilic acyl substitution C. electrophilic acyl substritution D. addition correct answers B The acyl group is A. C=O B. HC=O C. RC=O correct answers C Which of the following compounds would be most reactive? A. ethyl acetate B. propanamide C. benzoyl chloride D. phenyl anhydride correct answers C Which of the following compounds would have the most stabilized carbonyl group? ...

Alcohol - Ketone - Amine - Ether - Amide - Ester - functional groups - Alkyl - An alkane missing a hydrogen Aromatic compound - Cyclic, planar, with every atom of the aromatic ring having a p orbital, while obeying hackles rule of 4n+2 pi electrons Vinyl - Hydrolysis Reaction - Carboxylic Acid - pKa ~ 5 Enantiomers - stereoisomers that are non super imposable mirror images Diastereomers - - Same molecular formula, same bond connections, NOT mirrors...

Electrophilic Aromatic Substitution Nucleophilic Aromatic Substitution Elimination Addition what reagent is used to convert O= to alkyl and OH group? CH3Li and H3O+ what reagent is used to convert alcohol group to alkene?

electrophiles - ANSWERelectron seeking reagents that have room to accept a electron pair nucleophiles - ANSWERreagents seeking a nucleus to which to donate a pair of electrons proton transfer or protonation reaction - ANSWERthe transfer of a proton from one base to another transition state - ANSWERlying between the products and reactants free energy of activation (delta G double dagger) - ANSWERthe height of the barrier, the energy that the reactants attain in reaching the the transi...

Cumulated Diene correct answers double bonds are adjacent Conjugated Diene correct answers double bonds separated by 1 single bond Isolated Diene correct answers double bonds separated by more than 1 single bond Heteroatoms correct answers may be involved in conjugated dienes atom that isn't a carbon atom Diene Formation correct answers elimination using a strong, bulky base t-BuOK Single Bonds in Conjugated Diene correct answers shorter than typical will freely rotate allows...

Organic Chemistry ACS Final Exam Questions With Correct Verified Solutions A+ Graded Basicity rules - ANS -strong base: unstable/reactive (ED groups) -weak base: stable (EW groups/more EN/bigger) Chair conformation - ANS -more stable equatorial (slanted) -pointing up/pointing down=cis if both up -elimination: trans and diaxial Newman projection - ANS -gauche: substituent groups adjacent to each other -grab middle and turn to put in plane Enantiomers - ANS -not superimpos...

electrophiles - ANSWERelectron seeking reagents that have room to accept a electron pair nucleophiles - ANSWERreagents seeking a nucleus to which to donate a pair of electrons proton transfer or protonation reaction - ANSWERthe transfer of a proton from one base to another transition state - ANSWERlying between the products and reactants free energy of activation (delta G double dagger) - ANSWERthe height of the barrier, the energy that the reactants attain in reaching the the transi...

CHEM 210 Reactions Test Questions and Answers All Correct Describe the mechanism for the electrophilic addition of a strong acid. - Answer-Step 1) An alkene grabs a hydrogen off of a strong acid, forming a carbocation intermediate. Step 2) The conjugate base of the acid (an anion now) bonds to the open shell carbocation What is the regioselectivity of electrophilic addition reactions? - Answer-Markovnikov What is Markovnikov regioselectivity? - Answer-States that the major product is det...

Write complete names for the following: a) (S,S)-3,5-dihydroxycyclohexanone b) (E)-5-methyl-4-oxo-5-heptenal c) 4-methoxy-2-nitrobenzaldehyde d) 1-methyl-3-methylthio-2,4,6-cycloheptatrienol e) CHEM 335 Final Exam Questions and Answers | Verified Answers| Updated 2024/2025 2/11 pentamethylcyclopentadienyl anion 2. (15 points) Write accurate structures for the following: a) a chiral allene b) 18-crown-6 c) the HOMO of 1,3,5-hexatriene d) benzyl isobutyl disulfide e) the hydrat...

Chem 210 Exam II Questions & Answers 10electrophiles - ANSWERelectron seeking reagents that have room to accept a electron pair nucleophiles - ANSWERreagents seeking a nucleus to which to donate a pair of electrons proton transfer or protonation reaction - ANSWERthe transfer of a proton from one base to another transition state - ANSWERlying between the products and reactants free energy of activation (delta G double dagger) - ANSWERthe height of the barrier, the energy that the reac...