Mcpba - Study guides, Class notes & Summaries

Alcohol - Ketone - Amine - Ether - Amide - Ester - functional groups - Alkyl - An alkane missing a hydrogen Aromatic compound - Cyclic, planar, with every atom of the aromatic ring having a p orbital, while obeying hackles rule of 4n+2 pi electrons Vinyl - Hydrolysis Reaction - Carboxylic Acid - pKa ~ 5 Enantiomers - stereoisomers that are non super imposable mirror images Diastereomers - - Same molecular formula, same bond connections, NOT mirrors...

OsO4 and (H2O or Na2SO3) // KMnO4 and (NaOH or H2O) - ANSWEROH/OH dihydroxylation syn RCO3H or mCPBA - ANSWEREpoxidation add O to make an epoxy. Most substituted double bond reacts first X2 and (H2O or XOH) - ANSWER(X/OH)Halohydrin formation epoxy ion intermediate, anti, markovnikov, H2O added to more sub. carbon Cl2 or Br2 - ANSWERHalogenation, anti, epoxy ion intermediate H2O and H2SO4 - ANSWER(H/OH) Hydration, syn and anti addition, markovnikov, C+ intermediate, can make keto if i...

H-X CCl4 ADD STRONG ACIDS, -hydrohalogens - Mark w H-shift + cat. (X= Cl, Br, I) SYN+ANTI H2O H2SO4 ADD WEAK ACIDS, -hydration -Mark SYN + ANI Cl2, Br2, I2 CCl4 ADD X2 (Cl, Br, I), halogenation ANTI Cl2, Br2, I2 H2O / R-OH ADD halogen and OH halohydrin ANTI 1) NCS, NBS, NIS 2) H2O / R-OH ADD halogen and OH halohydrin ANTI H-OX/ R-OX (X=Cl, Br, I) ADD halogen (X) and OH halohydrin ANTI 1) BH3 2) NaOH, H2O2 ADD OH and H hydrobo...

OsO4 and (H2O or Na2SO3) // KMnO4 and (NaOH or H2O) - ANSWEROH/OH dihydroxylation syn RCO3H or mCPBA - ANSWEREpoxidation add O to make an epoxy. Most substituted double bond reacts first X2 and (H2O or XOH) - ANSWER(X/OH)Halohydrin formation epoxy ion intermediate, anti, markovnikov, H2O added to more sub. carbon Cl2 or Br2 - ANSWERHalogenation, anti, epoxy ion intermediate H2O and H2SO4 - ANSWER(H/OH) Hydration, syn and anti addition, markovnikov, C+ intermediate, can make keto if i...

BIOCHEM 2 LAB FINAL EXAM REVIEW 2024/2025 A+ GRADED Which of the following mol- ecules are steroids? (se- lect all that apply) Continues...

Organic Chemistry Chem 202): Top Exam Questions & Answers, 100% Accurate. Verified. H–Br Markovnikov addition of Br onto more substituted carbon H–Br, ROOR, heat Anti–Markovnikov addition of Br onto least substituted carbon Br2 heat Br Addition to more substituted carbon Br2, H2O2 Br addition to least substituted carbon H2SO4 (aq) Markovnikov addition of OH onto more substituted carbon Hg(OAc)2, H2O, NaBH3, –OH Markovnikov addition of OH onto more substituted carbon ...

less the more s character a carbocation has, the _____stable it is the same as when looking at an epoxide, the orientation around the oxygen is _________ the orientation around the double bond in the reactant BrOH when added with base makes an epoxide Br2 adds 2 Brs in anti conformation lindlar catalyst produces a Z alkene from an alkyne (adds 2 Hs in syn) add more electronegative atom, add pi bond 2 ways of producing an oxidation reaction remove e...

Br-Br (what is name) hallogenation Br-Cl (what is name) hallogenation Br-Cl / OH or H2O (what is name) hallogenation NBS (5 member ring w N, 2 2x O, and a hallogen attached) / strong nuc (what is name) hallogenation KMnO4 or OSO4 (what is name) diol "MCPBA" (R-C=O & -OOH) (what is name) epoxidation O3 / Zn (what is name) reductive ozonolysis O3 / NaOH, H2O, H2O2 (what is name) oxidative ozonolysis BH3 / H2O, H2O2, NaOH (what is na...

enantiomers are formed from __________ carbocation - achiral __________ are formed from chiral carbocation - enantiomers grignard reagents attack (most/least?) substituted epoxide? - least grignard reagents are used for (carbanion/carbocation?) generation. - carbanion we wat to use grignard reagents in (acidic/non-acidic?) conditions. - non-acidic if acidic conditions, it will suffer proton transfer hyperconjugation is (de/stabilizing?) for carbanions. - desta...

Organic Chem II - Exam 2 Question Bank questions and answers well illustrated. A(n) ______ group contains sulfur bonded to hydrogen. - correct answers.Thiol or mercapto Low temperatures are used to achieve- A) Thermodynamic control B) Reactant control C) Kinetic control D) Product control E) None of the above - correct answers.C) Kinetic control What is the purpose of dimercaprol, and how does it work? - correct answers.Dimercaprol is used to treat mercury and lea...