Chem 210

H-X CCl4 ADD STRONG ACIDS, -hydrohalogens - Mark w H-shift + cat. (X= Cl, Br, I) SYN+ANTI H2O H2SO4 ADD WEAK ACIDS, -hydration -Mark SYN + ANI Cl2, Br2, I2 CCl4 ADD X2 (Cl, Br, I), halogenation ANTI Cl2, Br2, I2 H2O / R-OH ADD halogen and OH halohydrin ANTI 1) NCS, NBS, NIS 2) H2O / R-OH ADD halogen and OH halohydrin ANTI H-OX/ R-OX (X=Cl, Br, I) ADD halogen (X) and OH halohydrin ANTI 1) BH3 2) NaOH, H2O2 ADD OH and H hydrobo...

Br-Br (what is name) hallogenation Br-Cl (what is name) hallogenation Br-Cl / OH or H2O (what is name) hallogenation NBS (5 member ring w N, 2 2x O, and a hallogen attached) / strong nuc (what is name) hallogenation KMnO4 or OSO4 (what is name) diol "MCPBA" (R-C=O & -OOH) (what is name) epoxidation O3 / Zn (what is name) reductive ozonolysis O3 / NaOH, H2O, H2O2 (what is name) oxidative ozonolysis BH3 / H2O, H2O2, NaOH (what is na...

Choose the most CORRECT property of an organic compound. A) low boiling point B) high melting point C) conducts current D) flammable E) A and D Answer: E) A and D A) Low boiling point AND D) Flammable Which of the following compounds will have double bond(s) in it? A) octane B) heptyne C) benzene D) A and C E) A and B Answer: D) A)Octane AND C)Benzene What is the molecular formula of cyclohexane? A) C6H8 B) C6H12 C) C6H10 D) C6H14 Answer: B) C6H12 ...

Linear 2 bonds, 180° Trigonal planar 3 bonds, 120° Tri-plan; bent 2 bonds, 1 lone pair, 120° Tetrahedral 4 bonds; 109.5° Tetra; trigonal pyramidal 3 bonds, 1 lone pair; 109.5° Tetra; bent 2 bonds, 2 lone pairs; 109.5° Trigonal bipyramidal 5 bonds; 120° or 90° Tri bi; seesaw 4 bonds, 1 lone pair; 120° or 90° Tri bi; T-shaped 3 bonds, 2 lone pairs; 120° or 90° Tri bi; linear 2 bonds, 3 lone pairs: 120° or 90° ...

Bronsted-Lowry acid proton donor (H+) and donates Electron Bronsted-Lowry base proton acceptor (H+), accepts electron HI ( give pKa, Conjugate Base, and reasons) -10, I^-(iodide), noble gas like configuration, large orbitals(less electron repulsion) somewhat electronegative HCl ( give pKa, Conjugate Base, and reasons) -7, Chloride(Cl^-), noble gas-like, electronegative H3O^+(Hydronium)- ( give pKa, Conjugate Base, and reasons) -2, H2O, neutral charge, electroneg...

electrophiles electron seeking reagents that have room to accept a electron pair nucleophiles reagents seeking a nucleus to which to donate a pair of electrons proton transfer or protonation reaction the transfer of a proton from one base to another transition state lying between the products and reactants free energy of activation (delta G double dagger) the height of the barrier, the energy that the reactants attain in reaching the the transition state e...

what factors explain the outcomes of reactions? hybridization, delocalization, eN, atom density what is a leaving group? - group of atom(s) that can be stable on its own - eN atoms that are good LG also make strong acids what is the α carbon? C directly attached to leaving group what are β Cs? β Hs? βC: C(s) attached to α carbon βH: H(s) attached to βC what is a LB? is it a nucleophile or electrophile? lewis base, nucleophile what is nucleophilic ...

Ammonium NH4+ Hydronium H30+ Mercury (I) Hg2(2+) Acetate C2H3O2(-) Azide N3(-) Carbonate CO3(2-) Chlorate ClO3(-) Chlorite ClO2(-) Chromate CrO4(2-) Cyanide CN(-) dichromate Cr2O7(2-) dihydrogen phosphate H2PO4(-) Hydrogen carbonate (bicarbonate) HCO3(-) hydrogen phosphate HPO4(2-) hydrogen sulfate (bisulfate) HSO4(-) Hydroxide OH(-) Hypochlorite ClO(-) Nitrate ...

less the more s character a carbocation has, the _____stable it is the same as when looking at an epoxide, the orientation around the oxygen is _________ the orientation around the double bond in the reactant BrOH when added with base makes an epoxide Br2 adds 2 Brs in anti conformation lindlar catalyst produces a Z alkene from an alkyne (adds 2 Hs in syn) add more electronegative atom, add pi bond 2 ways of producing an oxidation reaction remove e...

What are the Bronsted-Lowry definitions of acid and base? Acids donate H+ and Bases accept H+ (BAAD) What is the difference between a strong acid and a weak acid? Give examples of each. Strong acids completely dissociate into anion and H+. Weak acids do not dissociate completely into anion and H+, they form an equilibrium system and reform acid and anion and H+ continuously. Strong acid ex. HCl and H2SO4 Weak acid ex. H3PO4 and HC2H3O2 What is the difference between a strong ...