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Class notes

Equilibrium

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Introduction to equilibrium

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  • August 3, 2021
  • 6
  • 2020/2021
  • Class notes
  • Brandi west
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samaelhelaly
Pre Lecture
Dynamic Equilibrium
At a certain point all ruins are reversiable
When the speed of forward and reverse reactions are equal
o so the concentrations of the reactants or products remain constant
then equilibrium is attained
rate of forward reaction rate of reverse reaction



The concept of Equilibrium
Physical equilibrium consists of a single substance
T
Ex Azole Hz0cg

Chemical equilibrium involves 2 or more substances

Ex Nz04cg F 2N02cg


for equilibrium we write A E B

As the rum progresses i
1 A decreases to a constant
2 B increases from 0 to a constant
3 When Ar B are constant equilibrium is achieved


Kfwd key
Krev

, The magnitude of K
K is ratio of products to reactants measure of reaction extent
Small k very little product mostly reactant no rxn
Large K mostly product very little reactant Gemgoes to completion
Intermediate k significantamount of product r reactant



A B K 105
AT B
5
A B Ks lo


Equilibrium Constant
related to concentration of reactants 8 products at equilibrium
has no units
AA t b B F cc d D
d
k ac CaD
a b
art B

where 1 ay for solid or liquid
e l
2 ay P for a
gax in bar
ay 2 Ex in mollL or M for a solute
3



Manipulating Equilibrium Constants
when we multiply a balanced equation
by n then we raise the
value of K to the power of n

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