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Organic Chemistry ACS Final Exam Study Questions and Answers with Complete Solution 2024

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Basicity rules - -strong base: unstable/reactive (ED groups) -weak base: stable (EW groups/more EN/bigger) Chair conformation - -more stable equitorial (slanted) -pointing up/pointing down=cis if both up -elimination: trans and diaxial Newman projection - -gauche: substituent groups adjace...

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  • August 7, 2024
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Organic Chemistry ACS Final Exam
Study Questions and Answers with
Complete Solution 2024
possiblea



. 8/7/24 acs

, Organic Chemistry ACS Final Exam Study Questions and Answers with Complete
Solution 2024


Basicity rules - -strong base: unstable/reactive (ED groups)
-weak base: stable (EW groups/more EN/bigger)

Chair conformation - -more stable equitorial (slanted)
-pointing up/pointing down=cis if both up
-elimination: trans and diaxial

Newman projection - -gauche: substituent groups adjacent to eachother
-grab middle and turn to put in plane

Enantiomers - -not superimposable mirror images
-same besides stereochemistry

Diastereomers - -mirror images but one stereocenter stays and another is changed

Meso - -at least two stereo centers

Alkene + HBr - -adds Markonikov

Fischer projection - -vertical plane: away
-horizontal plant: towards
-assign priorities
-turn 90 then put on side

Electrophilic addition to alkene - -forms carbocation
-E+ adds

1.Hg(OAc)2, H2o
2.NaBH4
alkene - -forms mercurnium ion
-no rearrangement
-Mark addition of OH

1. B2H2
2.H2O2, NaOH
alkene - -anti-Mark addition of OH
-syn addition of the H added

Br2 to alkene - -anti addition
-adds to both sides
-could be allylic shift; 1,2 and 1,4 mixture

1.H2o,H2SO4
2. HgSO4
alkyne - -Mark OH intermediate (enol)

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