100% satisfaction guarantee Immediately available after payment Both online and in PDF No strings attached
logo-home
Module 5 ocr chemistry notes £5.06
Add to cart

Lecture notes

Module 5 ocr chemistry notes

 15 views  0 purchase
  • Institution
  • OCR

Covers all the content in module 5 chemistry in detail

Preview 3 out of 25  pages

  • March 29, 2024
  • 25
  • 2023/2024
  • Lecture notes
  • Physical chemistry
  • All classes
All documents for this subject (13)
avatar-seller
jesutowusi
OCR Tr 2 Physical
Chemistry Notes

, How fast ? gas constant = 8 .

314

How an rate de measured experiment
·
Change implt - Alt overtime


pltmeter
·
regular interval . l It' incunc

*
Mass Lost

that balarec
reach on
produce gas! Place on
·
reachin

volume of : Gas syringe
gas produced speaked perod of time ide gas equation
·
over . Use

"Colow change" Colorimeter : Measures ansurbance of light -
more conce darker more light absorbed
.

12ca9s + Cl3 COCIsca9s -
City COCH2 lag) + Tags + H cags
Noprud lefts
Brown Colorless - All products colorless
.
-



Known diff of 12
plut calibration absorbance plot graph
·
cove .
conc measure on -




Calculating rate from graph
a

By
↳ rate (how fast) -
gradict c

·
Tangent
Tangent
·




Initial rate from graph -




·
use target & O minutes




Clock epenments
· how long it takes until we can't see cross
through beaker. colow change -

end point

quicker clock . Lester Ital rate of reacher .




·
Bassumphuns
·
tenn of reache remaus constant

of
Concentrate reacher does not
change significantly during the time paned of the
·
.
reacher

·
rachon has not proceeded too so when the end punt is see


-
rate of reachin remains constand doing time period measuries


Lodine Clock experiment
-
H2Ozcaas + 2Httca9s + 21-aags - 2 H2Ock + laccas
·
2S20s" + lecass- 2 lcaas + S40 .
"cass-when sodium tho sulfat reacts comi I reacts
with stack
gives deep blue /black color .




Change conce
~
, keep every thing else constances find order of rechon.


Rate Equahon Orders
Link Oste vol conc can of substance A+ B -*
C + 1)
~
rate = K [A]" [B] "orders of reaches : tall i how care of substance affects the rate -




·
moldm"s"'varccurent
·
Zero order : Aconc has no effect on rate e .

g
18 [A] x 2 rate doesn't
·
1st order ! Aconc has proportional change on rate .
e
.



g
18 [A]42 , ratcxz

2 18 [A] doubles than quadruples
↳ order : squared proportuna change on rate . rare


can only he determined experimetely

, Rare Eg Rate constant

· ↳ : allows as to equate rate concentration. only fisced o particular temp . A temp , Dk

Larger faster rate of reachun
. ↑ temps * Kinche , collide morc often , but conc remains constant

to make equance balanced value of K




=
Calculating rate
↑ Locample :
2NOcgs Orcgs
·
+ -
2N02cgs-reachen 2 order not resport to NO & 1st order col respect to 02

Calculate rate of reache
given conc
of NO" 3x10-3 On (10-3 . E = 700
, 000 Moldest
b
[B]
"
rate
: k [A]
= (100 , 000 mol-dm's' [3x10-3]" [110-3J't
-6 :

3 X10- Moldest


Calculating Rate Constant
Example : Nocg + COcgs + Dacgs-NOzg + (Ocg) ·
K :? NO second order , [0s02 zerwarder

curd = 1 .
5410"moldm rate of reache : 1 11 x10- moldm-3 su
.




rate : " [NO]
↳ : = (1 . 173 x 10" "moldmst) =
520 mol"dms"

o (1 .
5410-3 Moldo's 72

Rate Graphs
~ rare found by taking gradient a various points on a concentration-time .
graph
↳ rate concentrative graphs help us
identify the order
changes
in

rate constant rate anonles
· I equal
-
1 order

O
E o
② order Change in canc Changes
·
T


rare equally
Time
(As time A




Vieuanelamots
ratechanges -
2nd order


?

e
Time [A]



Half-life
· time it takes for half of the reactants to be used un- graph used to calcaltck
↳ 195 order reachers : half life independent of concentrates . Half life same length
.

t


Kee
Unt :




Initial Rates method
* repeat experiments several times but changing con cf A B > Jone & ahme ble
, wano know effects of
Changing
canc of each one on rate

Work out initial
· rate of each experiment

record concentratues of each experiments ther initial rates instable -
Workout orders wite rate equation

· Example
r = k [NOcgc] 2 Clecgn]
Tate 1 0 .
63 C122 1 order
NO = List order 0 63 : k
.



[NUcgs] + [Cl2cqc]

The benefits of buying summaries with Stuvia:

Guaranteed quality through customer reviews

Guaranteed quality through customer reviews

Stuvia customers have reviewed more than 700,000 summaries. This how you know that you are buying the best documents.

Quick and easy check-out

Quick and easy check-out

You can quickly pay through credit card for the summaries. There is no membership needed.

Focus on what matters

Focus on what matters

Your fellow students write the study notes themselves, which is why the documents are always reliable and up-to-date. This ensures you quickly get to the core!

Frequently asked questions

What do I get when I buy this document?

You get a PDF, available immediately after your purchase. The purchased document is accessible anytime, anywhere and indefinitely through your profile.

Satisfaction guarantee: how does it work?

Our satisfaction guarantee ensures that you always find a study document that suits you well. You fill out a form, and our customer service team takes care of the rest.

Who am I buying these notes from?

Stuvia is a marketplace, so you are not buying this document from us, but from seller jesutowusi. Stuvia facilitates payment to the seller.

Will I be stuck with a subscription?

No, you only buy these notes for £5.06. You're not tied to anything after your purchase.

Can Stuvia be trusted?

4.6 stars on Google & Trustpilot (+1000 reviews)

52510 documents were sold in the last 30 days

Founded in 2010, the go-to place to buy revision notes and other study material for 14 years now

Start selling
£5.06
  • (0)
Add to cart
Added