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SBI4U Grade 12 Biology Ontario Curriculum Macromolecules Notes CA$14.43   Add to cart
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SBI4U Grade 12 Biology Ontario Curriculum Macromolecules Notes
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Enjoy these detailed notes, directly from the Ontario Secondary School Grade 12 Curriculum, focussing on SBI4U! These extensively detailed notes should help you if you're studying for an exam or just love biology! Good luck!

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  • February 24, 2020
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  • 2017/2018
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Carbohydrates, Proteins, Lipids 2017-02-25
Biology Test Notes Page M1

Carbohydrates
• Store energy in all organisms
• Found in a Carbon, Hydrogen, Oxygen ratio of 1:2:1
◦ Essentially that’s (CH2O)n, where N ∈ℕ
• Types
◦ Monosaccharides (1 sugar)
◦ Oligosaccharides (2-3 monosaccharides)
◦ Polysaccharides (4 or more monosaccharides)

Monosaccharides
• Simple sugars that contain a chain of carbon atoms with two or more hydroxyl (-OH) groups
attached to the chain
• They’re distinguished using the following criteria

Number of Carbons Carbonyl Group
• n=3 →triose • Aldehyde → aldose
• n=4 →tetrose • Ketone → ketose
• n=5 →pentose In rings, ketoses have an
• n=6 →hexose additional carbon attached to
• n=7 →heptose the anomeric one. Illustration 1: Ribose
is an aldopentose.
The formula is (carbonyl group)+(# of carbons)+(ose)

• In water, the above chains actually form rings, using nucleophillic (-OH group) attacks
◦ A tetrose in water forms a furanose, with oxygen at the top of the ring
◦ A pentose in water forms a pyranose, with oxygen on the right of the ring
◦ If an aldehyde group was present, it’s now called a cyclic hemiacetal
◦ If a ketone group was present, it’s now called a cyclic hemiketal
◦ The carbon on the right hand side of the ring is the anomeric carbon,
which is a stereoisomer. It’ll allow the ring to change between α and β anomeres
▪ In an α isomer, hydrogen up, hydroxide down
▪ In aβ isomer, hydrogen down, hydroxide up “downright uplefting”




Illustration 2: An example of alpha and beta
isomers (a furanose excluding hydrogen)

, Carbohydrates, Proteins, Lipids 2017-02-25
Biology Test Notes Page M2

Oligosaccharides
• Contain 2 or 3 simple sugars that are attached using covalent bonds involving oxygen called
glycosidic linkages (which are essentially condensation reactions)
◦ The special name for two connected sugars is a disaccharide, and the following examples of
oligosaccharides are all disaccharides
• Maltose: product of the digestion of starch→ contains 2 α glucoses :α 1,4 glycosidic linkages




+H2O




• Sucrose: table sugar → contains 1 α glucose and 1 α fructose :α 1,2 glycosidic linkages




• Lactose: component of milk → contains 1β glucose+1β galactose :β1, 4 glycosidic linkages




+H2O




Reducing vs Non-Reducing Sugars
• Reducing sugars have a free OH group on the anomeric carbon, which allows the sugar to act as
a reducing agent when the carbonyl group (which is now an OH) becomes an carboxyl group
◦ Examples: Glucose and lactose
• Non-reducing sugars do not have this luxury, as the OH group is attached or linked elsewhere
◦ Example: Sucrose

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