These are detailed Revision Notes for Topic 1.10 of AQA A-Level Chemistry (Kp). They were written by me using a combination of the textbook and class notes. I will also be uploading the other topics and creating bundles.
Topics Included:
- Equilibrium constant Kp for homogenous systems
Equilibrium Constant, Kp
19.1 Equilibrium Constant Kp for Homogeneous Systems:
19.1 Equilibrium constant
- Many reversible reactions take place in the gas phase.
- Gaseous equilibria also obey the equilibrium law, but it is usual to express their Kp for homogeneous
concentrations in a different way using the idea of partial pressure. systems
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- The mole fraction of gas A = +"+)# !"#$% "' ()%
- The partial pressure of a gas in a mixture is found by multiplying the mole fraction of that gas by the
total pressure.
- Partial pressure of gas A = mole fraction of A x total pressure
- It is worked out the same way as Kc but using the partial pressures rather than concentrations.
e.g., 1.00 moles of PCl5 vapour are heated to 500K in a sealed vessel. The equilibrium
mixture, at a pressure of 625kPa, contains 0.600 moles of chlorine. Calculate Kp
- It is affected by Le Chatelier’s principle in the same way as Kc. Increasing the temperature of an
exothermic reaction pushes the equilibrium to the left and decreases Kp
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