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Summary Elements from the sea notes

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Detailed, concise and organised revision notes summarising the whole of topic 3 of A level Chemistry OCR B (salters advanced). This topic is elements from the sea and includes notes on the halogens, redox reactions, electrolysis, equilibrium, transporting and the benefits of chlorine, iodine-thiosu...

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  • Topic 3 - elements from the sea
  • September 21, 2022
  • 17
  • 2022/2023
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ELEMENTS
OF THE
SEA
TOMI

,"'
HANNEN


p block
- -




group 7
elements are the halogens

all have 7 electrons in their outer shell


most reactive of the non metals ,
non found naturally in element form
°
Fluorine and chlorine are the most abundant ,
bromine occurs in smaller quantities ,


iodine and astatine be artificially produced it short tired
is scarce can
only as is


and radioactive .





All halogen elements are diatomic molecules .
For example , Fz and Bra
which are linked through a
single coolest bond .
between a pair of atoms .





Halogen atoms achieve
stability by gaining an electron →
forming
a halide ion or
sharing an electron with another non metal


Physical properties

element FLUORINE CHLORINE BROMINE IODINE ASTATINE
Formula Fz Uz Br , Iz Asz
appearance at pale yellow pale green dark red volatile
shiny black black
temp liquid → solid → purple vapour solid
room .


gas gas vapour

melting point -2201,53k -1014,172k -7% 1141,387k 3004,573k ,
266k

boiling point -1884,85k -341,239k 591,332k 18401,457k 3401,613h
order
of reactivity I 2 3 4 5

Uses


# ☒ E- ☒ ④ $ -




going down
the
group
-

become darker in colour

melting and boiling point increase
-




-


charge from
gases

liquids → solids at room temp .




-

become less volatile
-




electronegativity decreases

, Est
-




CHEMICAL PROPERTIES
-




group of reactive elements , they tend to remove electrons from other elements
so that they can
complete their outer shell e.g .





2N a es,
t
Uz egg
→ 2. NaCl is ,

-
Na has lost electron - been oxidised
-

U has gained an electron -
is on
oxidising agent .




-
elements at the top of group 7 are the most reactive and strongest
oxidising agents this decreases down the
,
going group .




The of shell electrons
atom made of it 's nucleus and

core an is up inner .




chlorine the outer shell from the and the attraction for
↳ in is
father core


the extra electron is weaker .
Therefore fluorine higher up in the
group ,
,



gains
electrons more readily ,
to become a
negative ion
,
than chlorine
-

Fluorine is the most reactive member of the halogens and the strongest
oxidising agent .




reactions of the halogens with halide ions
if chlorine chemical
-

is added to potassium iodide there is a reaction and

the solution turns brown .
Iodine is produced .
HALF EQUATIONS


Uz Uz 24
-




↳ 2k Clear, Iz 2e
-




can
t 2kt lags → t
caq , t →


↳ Uz Iz 21 Iz 2e
-
- -




21 2cL canst →
-


t → can,
+
can cag ,

half equation ,
ions left out are known as spectator ions

-
each iodide ion loses an electron and is oxidised

each chlorine atom gains an electron i chlorine is the oxidising agent and
-



.




has been reduced
-
if bromine solution is added to iodide ions
:




↳ Bre 21 2B r lzcaas
-
-



t → t
can can can,

Orange lyellow → brown

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