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Summary AQA A Level Chemistry Rate Equations Notes £4.49   Add to cart

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Summary AQA A Level Chemistry Rate Equations Notes

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AQA A Level Chemistry Rate Equations Summarised Notes. Made these on iPad from textbook, youtube videos and exam questions.

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  • February 16, 2023
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  • 2022/2023
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RATE EQUATIONS
CALCULATING RATE FROM A GRAPH

in
Rate can be found from the gradient orange
a
cuse a
bigger section of the
graph

Rate can also be found from the of a tangent
foot on a curved line of best fit.

↳ With curves, draw a
tangent
across the
4 extend the line right graph
4 the gradient is the rate at the specific point on the curve.


y




"a tangent




THE RATE EQUATION ORDERS


The rate equation links rate with entrations of substances



rate =
k(AT"(B]*
conc. of substance
rate/moldmn-s- -

e.g. in
following
equ. A + B -> c+ D
rate constant
units vary




ORDERS OF REACTION
↳ an order is the power to which
- -
a conc. is raised to in the rate equation. It tells us how the cone of

the substance affects the rate.


·
ICROORDER: changes in conc. that have no effect on rate
e.g.
if (A] doubles then rate doesn't change.
·PORACR: changes in conc has a proportional change on rate e.g. if [A] doubles then rate

doubles.


INPORDER: changes in conc. has a
squared proportional change on a rate e.g. if [A] doubles then rate
quadruples.



!orders can
only be determined by an experiment, you can't work it out by looking at an equation.



The Rate Equation Rate a Constant

The rate equ. Links rate with cone of substances.




rate constant K -




a constant no that allows us to ->
only fixed at a particular temperature,

equate rate a conc. if the temperature changes so does the

rate constant. ('K'increases when temp

increases).

- the larger the value of is, the faster the rate of reaction.


we increase the temperature, the panicles have kinetic collide often, this increases
as more
energy a more


the rate

rate k/A]"/B]*
=





but the cone of the substances remain constant.
↳to make this
equ balance the value of multicoreace.


CALCULATING RATE


be calculated the rate equation.
rate can
by using
·




EXAMPLE: The following reaction was carried out in a lab.

2
NO,g +
O,(g) ->
2NOc(g)
It was found that the reaction is "order with respect to NO and I order with respect to 02. Calculate

the rate of reaction given the conc. of NO 3x10% and 0, is 1x10%. The rate constant in

700,000 mol "dm's-'

↳ 1: write rate expression

rate k(No] [0,]'
=




↳ 2: substitute the numbers


rate= 700,000 x (3x10%'x((x10) =
6.3x10 "moldmn"s

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