this document summarises the entire syllabus of periodicity and Gp 2 reactions for A level.
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Describe the reaction of sodium with cold water. Include balanced chemical equation.
Answer: Sodium has a very exothermic reaction with cold water producing hydrogen and a colourless solution of sodium hydroxide.
2Na + 2H2O ----> 2NaOH + H2
2.
Describe the reaction of magnesium with cold water and steam. Include balanced chemical equation.
Answer: Magnesium has a very slight reaction with cold water but burns in steam.
Mg + 2H2O ---> Mg(OH)2 + H2
Magnesium burns in steam with its typical white flame to produce white magnesium oxide and hydrogen.
Mg + H2O ----> MgO + H2
3.
Describe the reaction of Aluminium with cold water. Include balanced chemical equation.
Answer: Aluminium powder heated in steam produces hydrogen and aluminium oxide. The reaction is relatively slow because of the existing strong aluminium oxide layer on the metal, and the build-up of even more oxide during the reaction.
2Al + 3H2O ----> Al2O3 + 3H2
4.
Describe the reaction of silicon with water. Include balanced chemical equation.
Answer: silicon will react with steam at red heat to produce silicon dioxide and hydrogen.
Si + 2H2O ----> SiO2 + 2H2
5.
Describe the reaction of PHOSPHORUS, CHLORINE, SULFUR and ARGON with cold water.
Answer: NO REACTION
6.
Describe the reaction of Sodium with Oxygen. Include balanced chemical equation.
Answer: Sodium burns in oxygen with an orange flame to produce a white solid mixture of sodium oxide and sodium peroxide.
4Na + O2 ----> 2Na2O
7.
Describe the reaction of Magnesium with Oxygen. Include balanced chemical equation
Answer: Magnesium burns in oxygen with an intense white flame to give white solid magnesium oxide.
2Mg + O2 -----> 2MgO
8.
Describe the reaction of Aluminium with Oxygen. Include balanced chemical equation
Answer: Aluminium will burn in oxygen if it is powdered, otherwise the strong oxide layer on the aluminium tends to inhibit the reaction. If you sprinkle aluminium powder into a Bunsen flame, you get white sparkles. White aluminium oxide is formed.
3Al + O2 ----> Al2O3
9.
Describe the reaction of Silicon with Oxygen. Include balanced chemical equation
Answer: Silicon will burn in oxygen if heated strongly enough. Silicon dioxide is produced.
Si + O2 ----> SiO2
10.
Describe the reaction of Phosphorus with Oxygen. Include balanced chemical equation
Answer: White phosphorus catches fire spontaneously in air, burning with a white flame and producing clouds of white smoke - a mixture of phosphorus(III) oxide and phosphorus(V) oxide.
The proportions of these depend on the amount of oxygen available. In an excess of oxygen, the product will be almost entirely phosphorus(V) oxide.
For the phosphorus(III) oxide:
P4 + 3O2 -----> P4O6
For the phosphorus(V) oxide:
P4 + 5 O2 ------> P4O10
Content preview
PERIODICITY (AS & A2)
A. Period 3
In Period 3 of the Periodic Table, the 3s and 3p orbitals are filling with electrons
Na [Ne] 3s1
Mg [Ne] 3s2
Al [Ne] 3s2 3p1
Si [Ne] 3s2 3p2
P [Ne] 3s2 3p3
S [Ne] 3s2 3p4
Cl [Ne] 3s2 3p5
Ar [Ne] 3s2 3p6
1
, PERIODICITY (AS & A2)
1. Atomic radii
Trend: Atomic radius decreases across a period from left to right.
Explanation: Across a period, the number of protons and the number of electrons increase by one
with each successive element. The extra electrons added to the atoms occupy the same quantum
shell with practically the same shielding effect. However, the nuclear charge increases from left to
right. The increasing effective nuclear charge attracts the outer electrons more strongly and closer to
the nucleus.
2. ionic radii from Na+ → Si4+
trend: ionic radii decrease
explanation: from Na+ → Si4+,
There are the same number of shells
Same shielding effect
Ionic radius/nm
Nuclear charge is increasing
Hence the effective nuclear charge
increases, and the outer electrons are more
attracted to the nucleus. A cation has a
smaller size than its original atom.
Na+ Mg2+ Al3+ Si4+ P3- S2- Cl-
Period 3 ions
From P3- → Cl-
Trend: ionic radii decrease
Explanation: from P3- → Cl-,
There are the same number of shells
Same shielding effect
Nuclear charge is increasing
Hence the effective nuclear charge increases, and the outer electrons are more attracted to
the nucleus. An anion has a larger size than its original atom.
2
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