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Summary Key terms semester 2

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Pharmacy - physical pharmacy 1st and 2nd semester summaries Bullet points, key notes, images and diagrams

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  • June 6, 2023
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  • 2018/2019
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Key Terms

Solution-dispersion of molecules of a material in a liquid medium and is transparent

Suspension- a dispersion of solid particles of a material in a liquid medium and is
generally cloudy

Colloid- suspension where particles are 0.1-1μm

Stern (fixed) layer- attraction of opposite charges to particle surface partially neutralise
the surface charge of the particle (counter-ions)

Diffuse Layer- co-ions neutralise the surface charge but are mobile

Shear Plane- barrier between the fixed and diffuse layers with counter-ions in the fixed
layer and co-ions in the diffuse layer

ζ Potential- governs electro-kinetic behaviours of a particle and is the potential
difference between the surface of the particle and the bulk medium

Coalescence- 2 particles collide and merge to form one bigger particle

Ostwald Ripening- evaporation of atoms from a cluster which transfer to another cluster

Emulsion- 2 immiscible liquids with 2 phases (continuous and dispersed) and droplet
size 1-100 μm

Interfacial tension- work required to increase the area of contact between 2 phases

Cracking- phase separation in an emulsion

Surface tension (γ)- cohesive forces between liquid molecules responsible for surface
tension

Stress (σ)- force per unit area

Strain (ε)- deformation of a body in response to a stress

Shear stress (σ)- force per unit area required to cause flow

Shear strain (γ)- velocity gradient or difference in velocity between 2 planes of a liquid

Viscosity (η)- resistance of a fluid to flow

Reduced Viscosity (ηsp/C)- ratio between specific viscosity and concentration

Specific Viscosity (ηsp)- relative increase in viscosity of the solution/viscosity of the
solvent

Shear Thinning- viscosity decreases with increased shear rate

Shear Thickening- viscosity increases with shear rate

Thixotropy- time dependant shear thinning

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