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Chemistry Edexcel A Level Equilibrium I &II Summary Sheet £3.49
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Chemistry Edexcel A Level Equilibrium I &II Summary Sheet

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Chemistry Edexcel A level summary sheet of Equilibrium I and II.

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  • March 17, 2024
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  • 2023/2024
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jodie2
le chatelier's principle rate yield compromises K expressions
↳ concentration of reactants ↑ ↳ haber process ↳ K is equilibrium constant

shifts to aA bBEcC dD
RHS N2 3H2(9) = 2NH3
+
=> =>
(9) + (g) : -
NH +



↳ concentration of products
4 => temperature decrease in yield & Ke : SDJd
( C) '
,



Shifts to CHS
=> => pressure ↑ ,
increase in yield [A]"(B) b
pressure 4 high cost
°
↳ => 450 C -
higher means low yield
=> shifts to side with fewer moles - lower means slow rate & KC of a reaction only changes if

of gas => 300atm - higher means small increase + high cost temperature changes
↳ temperature & e lower means slow rate ↳
homogeneous reactants + products are

=> shifts to endo thermic direction ↓ contact process in same physical state

↳ catalyst has no effect on equilibrium - S0219) +
E0219)
-
> SO319) : -
WH
↳ heterogeneous reactions + products
position are not in same physical state
↳ solids are ignored in K > expressions

Dynamic equilibrium - Kc 1 => equilibrium is half way
EQUI
=




↳ reactants + products are constantly 32 U ↳ K 1 => equilibrium lies On RHS

moving ↳ more product
↳ rate of toward = rate of backwards - O ↳ KC < 1 => equilibrium lies on LHS

↳ concentration of reactants + products is ↳ more reactants
constant calculations

↳ closed system
↳ 0 .
100 mol of ethylethanoate are added to 0 100
.
mol of water
. reaction conditions equilibrium constant
↳ isolated system the mixture is made up to Idm3. At equilibrium 0 0654 mol of .

water ↳ 2H((g) =H2(g) + (2(g) + WH

(H2) [12]
↳ reaction is reversible is present Calculate . Kc :
kc =
kp = P(H2) p((z)
[H1]2 2
P(H1)
CH3100CzH5 /K + H2OCK - CH3COOH(1) + CzH5OH(I)
kp expressions ni 0 100 temperature & [H2][12] increases

↓ +004) Forsted
.
0 .
100 n ,



4

↳ kp is
aA(g) + bB(g) =

equilibrium
c((g)
constant
+ dD(g)
in terms
nc


ne
-
0

0 0654
.
.
0346
↓ -
0 0346
.




0 0654
.
0 0346
.
0 6346
.

CH1] decreases

works the same for kp
: KI &



partial pressure [Se 0 0654/1 0 0654/1 0 0346/, 0 0346/ & KC and kp only affected by
.


of are
. .
.




d

kp P(((g)'p(D(g)
= temperature
KC [CHyCOOH] [CzH50H]
p(A(g)" P(B(g) :
: 0 0346 X0 8346
.
.


= 0 28
.




(CH310U(zHj] CH20] 0 0654
.
x 0 0654
. unitless
& for heterogeneous reaction : solids
+
liquids are ignored ↳ forkp :
P(A) =
P+ x
1
- total pressure x mole traction
n
kp only changes if temperature :
(A :
RA/H-
changes

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