CHEM 210 Final Exam Reactions, 2024.
P450
[O]
Breaks a double bond (even phenyl) to have add an oxygen that is bonded to each carbon of a double bond
Rh/ Pt
Dehydrogenation to form a double bond
Br2
FeBr3 (cat)
Adds a Br in the place of a hydrogen
BH2-H
Breaks triple OR double bond and ad...
CHEM 210 Final Exam Reactions, 2024.
P450
[O]
Breaks a double bond (even phenyl) to have add an oxygen that is bonded to each
carbon of a double bond
Rh/ Pt
Dehydrogenation to form a double bond
Br2
FeBr3 (cat)
Adds a Br in the place of a hydrogen
BH2-H
Breaks triple OR double bond and adds H or BH2 to those carbons
H2
NaNH3
Trans partial reduction of triple to double bonds
H2
Lindrar's catalyst
Cis partial reduction of triple to double bonds
H2, Pd/C or PtO2
Full hydrogenation of all double and triple bonds to a single bond
syn addition
(1)O3
(2) Reductive workup (Zn, C2S, PPh3)
Breaks double bond and puts oxygen at either end but leaves H
Phenyl groups not cleaved
(1)O3
(2) Oxidative workup (H2O2)
Breaks double bond and puts oxygens at either end + transforms H into OH
Phenyl groups not cleaved
m-CPBA
alkene to epoxide
Adds an oxygen that is bonded to each carbon of a double bond
OsO4
NaHSO3 workup
Breaks double bonds and adds OHs
KC4H9O
Good Base for E2
, Tosylate (TsO-)
Triflate (TfO-)
Mesylate (MsO-)
OsO4
NaHSO3 workup
Breaks double bonds and adds OHs
KHnO4 +NaOH
H2O
Syn addition of 2 OH groups
Lewis Acid
accepts a pair of nonbonding electrons
Lewis Base
Source of nbe pair
carbocation
Open shell carbon w positive charge
carboanion
Negatively charged carbon
hydrogen bond donor
strongly electronegative atom such as N, O, or F
hydrogen bond acceptor
electronegative atom with long electron pairs
Bronsted Acid
Molecule that provides H+
Bronsted Base
Molecule with a lone pair of nbe that accepts H+
The benefits of buying summaries with Stuvia:
Guaranteed quality through customer reviews
Stuvia customers have reviewed more than 700,000 summaries. This how you know that you are buying the best documents.
Quick and easy check-out
You can quickly pay through credit card for the summaries. There is no membership needed.
Focus on what matters
Your fellow students write the study notes themselves, which is why the documents are always reliable and up-to-date. This ensures you quickly get to the core!
Frequently asked questions
What do I get when I buy this document?
You get a PDF, available immediately after your purchase. The purchased document is accessible anytime, anywhere and indefinitely through your profile.
Satisfaction guarantee: how does it work?
Our satisfaction guarantee ensures that you always find a study document that suits you well. You fill out a form, and our customer service team takes care of the rest.
Who am I buying these notes from?
Stuvia is a marketplace, so you are not buying this document from us, but from seller NurseAdvocate. Stuvia facilitates payment to the seller.
Will I be stuck with a subscription?
No, you only buy these notes for £6.49. You're not tied to anything after your purchase.
